Literature DB >> 25641706

Electrophilic amination: the case of nitrenoids.

Pavel Starkov1, Timothy F Jamison, Ilan Marek.   

Abstract

Among the numerous approaches and reagents employed for electrophilic amination, nitrenoids have long stayed out of the limelight. Here, we systematically review the discovery, structural features and chemical reactivity of these promising reagents. We highlight advances in applying the chemistry of nitrenoids as well as outline current limitations and future directions.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  amination; amines; nitrenoids; nitrogen; synthetic methods

Year:  2015        PMID: 25641706     DOI: 10.1002/chem.201405779

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  13 in total

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Journal:  Angew Chem Int Ed Engl       Date:  2017-12-05       Impact factor: 15.336

2.  Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.

Authors:  Pavel Starkov; Jared T Moore; Douglas C Duquette; Brian M Stoltz; Ilan Marek
Journal:  J Am Chem Soc       Date:  2017-07-07       Impact factor: 15.419

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Authors:  Mahesh P Paudyal; Adeniyi Michael Adebesin; Scott R Burt; Daniel H Ess; Zhiwei Ma; László Kürti; John R Falck
Journal:  Science       Date:  2016-09-09       Impact factor: 47.728

4.  Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals.

Authors:  Zhe Zhou; Zhiwei Ma; Nicole Erin Behnke; Hongyin Gao; László Kürti
Journal:  J Am Chem Soc       Date:  2016-12-23       Impact factor: 15.419

5.  Photocatalytic Aminodecarboxylation of Carboxylic Acids.

Authors:  Simon B Lang; Kaitie C Cartwright; Richard S Welter; Theresa M Locascio; Jon A Tunge
Journal:  European J Org Chem       Date:  2016-06-19

6.  Rapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds.

Authors:  Hongyin Gao; Zhe Zhou; Doo-Hyun Kwon; James Coombs; Steven Jones; Nicole Erin Behnke; Daniel H Ess; László Kürti
Journal:  Nat Chem       Date:  2016-11-28       Impact factor: 24.427

7.  Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes.

Authors:  Pericles Stavropoulos
Journal:  Comments Mod Chem A Comments Inorg Chem       Date:  2016-04-29       Impact factor: 4.533

8.  Testing the limits of radical-anionic CH-amination: a 10-million-fold decrease in basicity opens a new path to hydroxyisoindolines via a mixed C-N/C-O-forming cascade.

Authors:  Quintin Elliott; Gabriel Dos Passos Gomes; Christopher J Evoniuk; Igor V Alabugin
Journal:  Chem Sci       Date:  2020-02-21       Impact factor: 9.825

9.  Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium-Assisted Multicomponent Reactions.

Authors:  Torsten Roth; Hubert Wadepohl; Eric Clot; Lutz H Gade
Journal:  Chemistry       Date:  2015-11-06       Impact factor: 5.236

10.  Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides.

Authors:  Marina Zenzola; Robert Doran; Leonardo Degennaro; Renzo Luisi; James A Bull
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-29       Impact factor: 15.336

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