Literature DB >> 25639259

Synthesis of main-chain metal carbonyl organometallic macromolecules (MCMCOMs).

Kai Cao1, Nimer Murshid, Xiaosong Wang.   

Abstract

Synthesis of main-chain metal carbonyl organometallic macromolecules (MCMCOMs) is difficult, mainly due to the instability of metal carbonyl complexes. Despite its challenge a number of MCMCOMs has been prepared by strategically using organometallic, organic, and polymer synthetic chemistry. Main contributions to this research field were reported by the groups of Tyler, Pannell, and Wang and are briefly summarized in this article.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Keywords:  metal acyl; metal-carbonyl; migration insertion; organometallic macromolecules; polymerization

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Year:  2015        PMID: 25639259     DOI: 10.1002/marc.201400563

Source DB:  PubMed          Journal:  Macromol Rapid Commun        ISSN: 1022-1336            Impact factor:   5.734


  1 in total

Review 1.  Recent advances in metathesis-derived polymers containing transition metals in the side chain.

Authors:  Ileana Dragutan; Valerian Dragutan; Bogdan C Simionescu; Albert Demonceau; Helmut Fischer
Journal:  Beilstein J Org Chem       Date:  2015-12-28       Impact factor: 2.883

  1 in total

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