Literature DB >> 25631122

Initial radical cation pathway in the Mo2Cl10-mediated dehydrogenative arene coupling.

Jana Leppin1, Moritz Schubert, Siegfried R Waldvogel, Katja Heinze.   

Abstract

Experimental (EPR) and theoretical (DFT) evidence is provided for radical cation formation as initial step in the Mo2Cl10-mediated dehydrogenative arene coupling. The initial electron transfer from methoxyarenes to molybdenum proceeds via an inner sphere mechanism.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CC coupling; EPR spectroscopy; electron transfer; molybdenum; radical cations

Year:  2015        PMID： 25631122     DOI： 10.1002/chem.201406522

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


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