| Literature DB >> 25624507 |
Alexey Eremin1, Pemika Hirankittiwong2, Nattaporn Chattham2, Hajnalka Nádasi3, Ralf Stannarius3, Jumras Limtrakul4, Osamu Haba5, Koichiro Yonetake5, Hideo Takezoe1.
Abstract
A small amount of azo-dendrimer molecules dissolved in a liquid crystal enables translational and rotational motions of microrods in a liquid crystal matrix under unpolarized UV light irradiation. This motion is initiated by a light-induced trans-to-cis conformational change of the dendrimer adsorbed at the rod surface and the associated director reorientation. The bending direction of the cis conformers is not random but is selectively chosen due to the curved local director field in the vicinity of the dendrimer-coated surface. Different types of director distortions occur around the rods, depending on their orientations with respect to the nematic director field. This leads to different types of motions driven by the torques exerted on the particles by the director reorientations.Keywords: colloidal inclusions; elasticity; liquid crystals; photoisomerization; topological defects
Year: 2015 PMID: 25624507 PMCID: PMC4330760 DOI: 10.1073/pnas.1419850112
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205