Literature DB >> 25620413

Highly regioselective osmium-catalyzed hydroformylation.

Lipeng Wu1, Qiang Liu, Anke Spannenberg, Ralf Jackstell, Matthias Beller.   

Abstract

The first highly regioselective and general osmium-catalyzed hydroformylation of olefins to aldehydes is reported. The combination of Os3(CO)12 and imidazoyl-substituted phosphine ligands allows n-selective (up to 99%) hydroformylation of bulk aliphatic as well as functional alkenes in good yields (64-87%).

Entities:  

Year:  2015        PMID： 25620413     DOI： 10.1039/c4cc05626d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Osmium(0)-Catalyzed C-C Coupling of Ethylene and α-Olefins with Diols, Ketols, or Hydroxy Esters via Transfer Hydrogenation.

Authors:  Boyoung Y Park; Tom Luong; Hiroki Sato; Michael J Krische
Journal:  J Org Chem       Date:  2016-09-08       Impact factor: 4.354

2.  Accessing and predicting the kinetic profiles of homogeneous catalysts from volcano plots.

Authors:  Matthew D Wodrich; Michael Busch; Clémence Corminboeuf
Journal:  Chem Sci       Date:  2016-06-03       Impact factor: 9.825

3.  Hydration of Aliphatic Nitriles Catalyzed by an Osmium Polyhydride: Evidence for an Alternative Mechanism.

Authors:  Juan C Babón; Miguel A Esteruelas; Ana M López; Enrique Oñate
Journal:  Inorg Chem       Date:  2021-04-27       Impact factor: 5.165
  3 in total

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