| Literature DB >> 25619560 |
Yonghao Zheng1, Mao-sheng Miao, Géraldine Dantelle, Nancy D Eisenmenger, Guang Wu, Ilhan Yavuz, Michael L Chabinyc, Ken N Houk, Fred Wudl.
Abstract
A stable organic diradicaloid with an intermolecular quintet at room temperature as a polycrystalline solid is studied. The conclusion is supported by the observation of the ΔMs = ±2 forbidden transition, electron spin resonance (ESR) simulations, and density functional theory (DFT) calculations. In addition, the molecule, as the active component of a device, is an outstanding near-infrared photodetector with detectivity over 10(11) cm Hz(1/2) W(-1) at 1200 nm.Entities:
Keywords: diradicaloids; electron spin resonance; photodetectors; quintet states
Year: 2015 PMID： 25619560 DOI： 10.1002/adma.201405093
Source DB: PubMed Journal: Adv Mater ISSN： 0935-9648 Impact factor: 30.849