Literature DB >> 25594078

Eumelanin-inspired core derived from vanillin: a new building block for organic semiconductors.

Subhashini Selvaraju1, K A Niradha Sachinthani, RaiAnna A Hopson, Frederick M McFarland, Song Guo, Arnold L Rheingold, Toby L Nelson.   

Abstract

An eumelanin-inspired core derived from the natural product, vanillin (vanilla bean extract) was utilized for the synthesis of eumelanin-inspired small molecules and polymer via Sonogashira cross coupling. The materials demonstrate that the methyl 4,7-dibromo-5,6-dimethoxy-N-methyl-1H-indole-2-carboxylate core can serve as a new building block for organic semiconductors.

Entities:  

Year:  2015        PMID: 25594078     DOI: 10.1039/c4cc09011j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Expedient synthesis of eumelanin-inspired 5,6-dihydroxyindole-2-carboxylate ethyl ester derivatives.

Authors:  Andrew H Aebly; Jeffrey N Levy; Benjamin J Steger; Jonathan C Quirke; Jason M Belitsky
Journal:  RSC Adv       Date:  2018-08-07       Impact factor: 3.361

Review 2.  Vanillin: A Promising Biosourced Building Block for the Preparation of Various Heterocycles.

Authors:  David Gendron
Journal:  Front Chem       Date:  2022-07-07       Impact factor: 5.545

  2 in total

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