Literature DB >> 25588124

Modular and highly stereoselective approach to all-carbon tetrasubstituted alkenes.

Vladislav Kotek1, Hana Dvořáková, Tomáš Tobrman.   

Abstract

A modular and completely stereoselective approach for the construction of all-carbon tetrasubstituted alkenes is described. It is based on the three-fold, sequential metal-catalyzed, cross-coupling functionalization of simple enolphosphate dibromide templates with carbon nucleophiles, affording tetrasubstituted alkenes as single isomers.

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Year:  2015        PMID: 25588124     DOI: 10.1021/ol503624v

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Intramolecular Halogen Atom Coordinated H Transfer via Ion-Neutral Complex in the Gas Phase Dissociation of Protonated Dichlorvos Derivatives.

Authors:  Xiaoping Zhang; Shuai Cheng
Journal:  J Am Soc Mass Spectrom       Date:  2017-07-05       Impact factor: 3.109

2.  Formation of trisubstituted buta-1,3-dienes and α,β-unsaturated ketones via the reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents.

Authors:  Petr Oeser; Jakub Koudelka; Hana Dvořáková; Tomáš Tobrman
Journal:  RSC Adv       Date:  2020-09-22       Impact factor: 4.036

  2 in total

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