Literature DB >> 25563653

cis-Semihydrogenation of alkynes with amine borane complexes catalyzed by gold nanoparticles under mild conditions.

Eleni Vasilikogiannaki1, Ioannis Titilas, Georgios Vassilikogiannakis, Manolis Stratakis.   

Abstract

Supported gold nanoparticles catalyze the semihydrogenation of alkynes to alkenes with ammonia borane or amine borane complexes in excellent yields and under mild conditions. Internal alkynes provide cis-alkenes, making this protocol an attractive alternative of the classical Lindlar's hydrogenation.

Entities:  

Year:  2015        PMID: 25563653     DOI: 10.1039/c4cc08163c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Ligand-Promoted Iridium-Catalyzed Transfer Hydrogenation of Terminal Alkynes with Ethanol and Its Application.

Authors:  Chengniu Wang; Shengnan Gong; Zhipeng Liang; Yufeng Sun; Rui Cheng; Banghua Yang; Yirong Liu; Jinfei Yang; Fei Sun
Journal:  ACS Omega       Date:  2019-09-18

2.  Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH3BH3 or NaBH4 Catalyzed by Au Nanoparticles.

Authors:  Marios Kidonakis; Manolis Stratakis
Journal:  Nanomaterials (Basel)       Date:  2021-01-18       Impact factor: 5.076

  2 in total

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