Literature DB >> 25555172

Functional helquats: helical cationic dyes with marked, switchable chiroptical properties in the visible region.

Paul E Reyes-Gutiérrez1, Michael Jirásek, Lukáš Severa, Pavlína Novotná, Dušan Koval, Petra Sázelová, Jan Vávra, Andreas Meyer, Ivana Císařová, David Šaman, Radek Pohl, Petr Štěpánek, Petr Slavíček, Benjamin J Coe, Miroslav Hájek, Václav Kašička, Marie Urbanová, Filip Teplý.   

Abstract

Helquat dyes are the first helicene-like cationic styryl dyes obtained as separate enantiomers. Their remarkable chiroptical properties are due to the unique combination of a cationic hemicyanine chromophore and a helicene-like motif. The magnitude of the ECD response and the pH switching along with their positioning in the visible region are unprecedented among helicenoids.

Entities:  

Year:  2015        PMID: 25555172     DOI: 10.1039/c4cc08967g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Physicochemical and Electronic Properties of Cationic [6]Helicenes: from Chemical and Electrochemical Stabilities to Far-Red (Polarized) Luminescence.

Authors:  Johann Bosson; Geraldine M Labrador; Simon Pascal; François-Alexandre Miannay; Oleksandr Yushchenko; Haidong Li; Laurent Bouffier; Neso Sojic; Roberto C Tovar; Gilles Muller; Denis Jacquemin; Adèle D Laurent; Boris Le Guennic; Eric Vauthey; Jérôme Lacour
Journal:  Chemistry       Date:  2016-11-25       Impact factor: 5.236

Review 2.  Synthesis of Functionalized Six-Membered-Ring Azahelicenes.

Authors:  Francesca Fontana; Benedetta Bertolotti
Journal:  Molecules       Date:  2022-04-14       Impact factor: 4.927

3.  Functionalized cationic [4]helicenes with unique tuning of absorption, fluorescence and chiroptical properties up to the far-red range.

Authors:  I Hernández Delgado; S Pascal; A Wallabregue; R Duwald; C Besnard; L Guénée; C Nançoz; E Vauthey; R C Tovar; J L Lunkley; G Muller; J Lacour
Journal:  Chem Sci       Date:  2016-04-08       Impact factor: 9.825

  3 in total

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