| Literature DB >> 25539406 |
Satoru Ito1, Satoru Hiroto, Sangsu Lee, Minjung Son, Ichiro Hisaki, Takuya Yoshida, Dongho Kim, Nagao Kobayashi, Hiroshi Shinokubo.
Abstract
Highly twisted π-conjugated molecules have been attractive but challenging targets. We report here an efficient synthesis of highly twisted diporphyrins with 126° and 136° twist angles that involves an oxidative fusion reaction of planar aminoporphyrin precursors at room temperature. Repeated amination-oxidative fusion sequences provide a unidirectionally twisted tetramer. The twisting angle of the tetramer is 298°.Entities:
Year: 2014 PMID： 25539406 DOI： 10.1021/ja511905f
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419