Literature DB >> 25532950

Cold and controlled molecular beams: production and applications.

Justin Jankunas1, Andreas Osterwalder.   

Abstract

The field of cold molecules has become an important source of new insight in fundamental chemistry and molecular physics. High-resolution spectroscopy benefits from translationally and internally cold molecules by increased interaction times and reduced spectral congestion. Completely new effects in scattering dynamics become accessible with cold and controlled molecules. Many of these experiments use molecular beams as a starting point for the generation of molecular samples. This review gives an overview of methods to produce beams of cold molecules, starting from supersonic expansions or effusive sources, and provides examples of applications in spectroscopy and molecular dynamics studies.

Keywords:  cold chemistry; cold molecules; spectroscopy

Year:  2014        PMID: 25532950     DOI: 10.1146/annurev-physchem-040214-121307

Source DB:  PubMed          Journal:  Annu Rev Phys Chem        ISSN: 0066-426X            Impact factor:   12.703


  8 in total

1.  Nuclear spin conservation enables state-to-state control of ultracold molecular reactions.

Authors:  Ming-Guang Hu; Yu Liu; Matthew A Nichols; Lingbang Zhu; Goulven Quéméner; Olivier Dulieu; Kang-Kuen Ni
Journal:  Nat Chem       Date:  2020-12-30       Impact factor: 24.427

2.  Strong non-Arrhenius behavior at low temperatures in the OH + HCl → H2O + Cl reaction due to resonance induced quantum tunneling.

Authors:  Xin Xu; Jun Chen; Xiaoxiao Lu; Wei Fang; Shu Liu; Dong H Zhang
Journal:  Chem Sci       Date:  2022-06-13       Impact factor: 9.969

3.  Heavy-atom tunnelling in Cu(ii)N6 complexes: theoretical predictions and experimental manifestation.

Authors:  Itzhak Sedgi; Sebastian Kozuch
Journal:  Chem Sci       Date:  2020-02-18       Impact factor: 9.825

Review 4.  Observation of quantum dynamical resonances in near cold inelastic collisions of astrophysical molecules.

Authors:  Michel Costes; Christian Naulin
Journal:  Chem Sci       Date:  2016-01-07       Impact factor: 9.825

5.  Long-lasting field-free alignment of large molecules inside helium nanodroplets.

Authors:  Adam S Chatterley; Constant Schouder; Lars Christiansen; Benjamin Shepperson; Mette Heidemann Rasmussen; Henrik Stapelfeldt
Journal:  Nat Commun       Date:  2019-01-11       Impact factor: 14.919

6.  Considerable matrix shift in the electronic transitions of helium-solvated cesium dimer cation Cs2He.

Authors:  Lorenz Kranabetter; Nina K Bersenkowitsch; Paul Martini; Michael Gatchell; Martin Kuhn; Felix Laimer; Arne Schiller; Martin K Beyer; Milan Ončák; Paul Scheier
Journal:  Phys Chem Chem Phys       Date:  2019-11-08       Impact factor: 3.676

7.  Switch chemistry at cryogenic conditions: quantum tunnelling under electric fields.

Authors:  Omer Kirshenboim; Alexander Frenklah; Sebastian Kozuch
Journal:  Chem Sci       Date:  2020-12-15       Impact factor: 9.825

Review 8.  Optimal beam sources for Stark decelerators in collision experiments: a tutorial review.

Authors:  Sjoerd N Vogels; Zhi Gao; Sebastiaan Yt van de Meerakker
Journal:  EPJ Tech Instrum       Date:  2015-08-06
  8 in total

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