Direct fabrication of nanoporous graphene from graphene oxide by adding a gasification agent to a magnesiothermic reaction.

CaCO3 acts as a gasification agent during magnesiothermic reduction of graphene oxide, thus preventing the newly formed graphene from restacking. The surface area of the obtained graphene increases from 66 m(2) g(-1) to 603 m(2) g(-1) by adding CaCO3 with a high yield of ∼70% based on the carbon content in graphene oxide.