Literature DB >> 25531826

Synthesis and characterization of 1,2,3,4,5-pentafluoroferrocene.

Karlheinz Sünkel1, Stefan Weigand, Alexander Hoffmann, Sebastian Blomeyer, Christian G Reuter, Yury V Vishnevskiy, Norbert W Mitzel.   

Abstract

Starting from ferrocene, pentafluoroferrocene [Fe(C5F5)(C5H5)] can be prepared in five steps via a one-pot lithiation-electrophilic fluorination strategy. Pentafluoroferrocene was characterized by multinuclear NMR and IR spectroscopy, by cyclovoltammetry as well as X-ray (solid) and electron diffraction (gas) and the experimental results compared with DFT calculations.

Entities:  

Year:  2014        PMID: 25531826     DOI: 10.1021/ja511588p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  Molecular structures of the pentaphenylcyclopentadienyl iron complexes [(C5Ph5)Fe(CO)2R] (R = Me, Ph, iPr and Bu).

Authors:  Karlheinz Sünkel; Christian Klein-Hessling
Journal:  Acta Crystallogr C Struct Chem       Date:  2021-06-16       Impact factor: 1.172

2.  Polysubstituted ferrocenes as tunable redox mediators.

Authors:  Sven D Waniek; Jan Klett; Christoph Förster; Katja Heinze
Journal:  Beilstein J Org Chem       Date:  2018-05-07       Impact factor: 2.883

3.  Polar Metallocenes.

Authors:  Haiwu Zhang; B Yu Yavorsky; R E Cohen
Journal:  Molecules       Date:  2019-01-29       Impact factor: 4.411

  3 in total

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