Literature DB >> 25529550

Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex.

Eva Jürgens1, Barbara Wucher, Frank Rominger, Karl W Törnroos, Doris Kunz.   

Abstract

An efficient Rh(I)-NHC-pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methylketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by Lewis acids.

Entities:  

Year:  2015        PMID: 25529550     DOI: 10.1039/c4cc07154a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Deoxygenation of Epoxides with Carbon Monoxide.

Authors:  Theo Maulbetsch; Eva Jürgens; Doris Kunz
Journal:  Chemistry       Date:  2020-07-23       Impact factor: 5.236

  1 in total

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