| Literature DB >> 25528677 |
Indresh Kumar Pandey1, Mookan Natarajan1, Sandeep Kaur-Ghumaan2.
Abstract
The design, syntheses and characteristics of metal carbonyl complexes with aromatic dithiolate linkers reported as bioinspired hydrogenase catalytic site models are described and reviewed. Among these the complexes capable of hydrogen generation have been discussed in detail. Comparisons have been made with carbonyl complexes having alkyl dithiolates as linkers between metal centers.Entities:
Keywords: Alkyl/aromatic dithiolates; Bioinorganic chemistry; Hydrogenase models; Iron carbonyl complexes; Proton reduction
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Year: 2014 PMID： 25528677 DOI： 10.1016/j.jinorgbio.2014.11.006
Source DB: PubMed Journal: J Inorg Biochem ISSN： 0162-0134 Impact factor: 4.155