Literature DB >> 25521538

Intramolecular frustrated Lewis pair with the smallest boryl site: reversible H2 addition and kinetic analysis.

Konstantin Chernichenko1, Bianka Kótai, Imre Pápai, Vladimir Zhivonitko, Martin Nieger, Markku Leskelä, Timo Repo.   

Abstract

Ansa-aminoborane 1 (ortho-TMP-C6H4-BH2; TMP = 2,2,6,6-tetramethylpiperid-1-yl), a frustrated Lewis pair with the smallest possible Lewis acidic boryl site (-BH2), is prepared. Although it is present in quenched forms in solution, and BH2 represents an acidic site with reduced hydride affinity, 1 reacts with H2 under mild conditions producing ansa-ammonium trihydroborate 2. The thermodynamic and kinetic features as well as the mechanism of this reaction are studied by variable-temperature NMR spectroscopy, spin-saturation transfer experiments, and DFT calculations, which provide comprehensive insight into the nature of 1.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  aminoboranes; density functional calculations; frustrated Lewis pairs; kinetics; thermodynamics

Year:  2014        PMID： 25521538     DOI： 10.1002/anie.201410141

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

Review 1.  On the concept of frustrated Lewis pairs.

Authors:  Frédéric-Georges Fontaine; Douglas W Stephan
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

2.  Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols.

Authors:  Hua Zhang; Xiao-Yu Zhan; Yu Dong; Jian Yang; Shuai He; Zhi-Chuan Shi; Xiao-Mei Zhang; Ji-Yu Wang
Journal:  RSC Adv       Date:  2020-04-30       Impact factor: 4.036

3.  CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template.

Authors:  Tongdao Wang; Long Wang; Constantin G Daniliuc; Kamil Samigullin; Matthias Wagner; Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2017-01-04       Impact factor: 9.825

4.  Spontaneous 15N Nuclear Spin Hyperpolarization in Metal-Free Activation of Parahydrogen by Molecular Tweezers.

Authors:  Kristina Sorochkina; Vladimir V Zhivonitko; Konstantin Chernichenko; Ville-Veikko Telkki; Timo Repo; Igor V Koptyug
Journal:  J Phys Chem Lett       Date:  2018-02-08       Impact factor: 6.475

5.  Parahydrogen-induced polarization with a metal-free P-P biradicaloid.

Authors:  Vladimir V Zhivonitko; Jonas Bresien; Axel Schulz; Igor V Koptyug
Journal:  Phys Chem Chem Phys       Date:  2019-03-13       Impact factor: 3.676

6.  Accurate Reduced-Cost CCSD(T) Energies: Parallel Implementation, Benchmarks, and Large-Scale Applications.

Authors:  László Gyevi-Nagy; Mihály Kállay; Péter R Nagy
Journal:  J Chem Theory Comput       Date:  2021-01-05       Impact factor: 6.006

Review 7.  Boron-Ligand Cooperation: The Concept and Applications.

Authors:  Max Hasenbeck; Urs Gellrich
Journal:  Chemistry       Date:  2021-01-28       Impact factor: 5.236

8.  Metal-Free C-H Borylation of N-Heteroarenes by Boron Trifluoride.

Authors:  Vladimir Iashin; Dénes Berta; Konstantin Chernichenko; Martin Nieger; Karina Moslova; Imre Pápai; Timo Repo
Journal:  Chemistry       Date:  2020-09-29       Impact factor: 5.236

9.  Synthesis of Intramolecular P/Al-Based Frustrated Lewis Pairs via Aluminum-Tin-Exchange and their Reactivity toward CO2.

Authors:  Patrick Federmann; Robert Müller; Fabian Beckmann; Caroline Lau; Beatrice Cula; Martin Kaupp; Christian Limberg
Journal:  Chemistry       Date:  2022-03-22       Impact factor: 5.020

10.  Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2.

Authors:  Sai Zhang; Zheng-Qing Huang; Yuanyuan Ma; Wei Gao; Jing Li; Fangxian Cao; Lin Li; Chun-Ran Chang; Yongquan Qu
Journal:  Nat Commun       Date:  2017-05-18       Impact factor: 14.919
  10 in total

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