| Literature DB >> 25517883 |
Zhiyong Guo1, Dan Yan, Hailong Wang, Daniel Tesfagaber, Xinle Li, Yusheng Chen, Wenyu Huang, Banglin Chen.
Abstract
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.Entities:
Mesh：
Substances：
Year: 2014 PMID： 25517883 DOI： 10.1021/ic502116k
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165