| Literature DB >> 25513732 |
Mark G McLaughlin1, Catherine A McAdam, Matthew J Cook.
Abstract
A rapid and stereodefined synthesis of MIDA-boryl vinylsilanes has been achieved through the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.Entities:
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Year: 2014 PMID： 25513732 DOI： 10.1021/ol503065a
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005