| Literature DB >> 25513725 |
Duyi Shen1, Chengxia Miao, Daqian Xu, Chungu Xia, Wei Sun.
Abstract
The manganese complex Mn(S-PMB)(CF3SO3)2 was proven to be highly efficient in the catalytic oxidation of several benzylic and aliphatic secondary alcohols with H2O2 as the oxidant and acetic acid as the additive. A maximum turnover number of 4700 was achieved in the alcohol oxidation. In addition, the Hammett analysis unveiled the electrophilic nature of this manganese catalyst with N4 ligand.Entities:
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Year: 2014 PMID： 25513725 DOI： 10.1021/ol5032156
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005