Literature DB >> 25505009

Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow.

Thomas S A Heugebaert1, Christian V Stevens2, C Oliver Kappe3.   

Abstract

Singlet-oxygen oxidation of 5-hydroxymethylfurfural (5-HMF) was performed in continuous flow mode using rose Bengal as photosensitizer. The resulting butenolide (H(2) MF) was formed selectively in high yield. The procedure proved to be scalable and applicable to related bio-based furfurals. Furthermore, preliminary data show that H(2) MF can be readily isomerized thermally to 5-hydroxy-4-keto-pentenoic acid oligomers.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  5-HMF; continuous flow; oxidation; photochemistry; singlet oxygen

Mesh：

Substances：

Year:  2014        PMID： 25505009     DOI： 10.1002/cssc.201403182

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  4 in total

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  4 in total

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