Literature DB >> 25493713

Reaction dynamics at liquid interfaces.

Ilan Benjamin1.   

Abstract

The liquid interface is a narrow, highly anisotropic region, characterized by rapidly varying density, polarity, and molecular structure. I review several aspects of interfacial solvation and show how these affect reactivity at liquid/liquid interfaces. I specifically consider ion transfer, electron transfer, and SN2 reactions, showing that solvent effects on these reactions can be understood by examining the unique structure and dynamics of the liquid interface region.

Entities:  

Keywords:  SN2 reaction; electron transfer; ion transfer; phase transfer catalysis

Year:  2014        PMID： 25493713     DOI： 10.1146/annurev-physchem-040214-121428

Source DB:  PubMed          Journal:  Annu Rev Phys Chem        ISSN： 0066-426X            Impact factor:   12.703


  3 in total

1.  Nanoscale view of assisted ion transport across the liquid-liquid interface.

Authors:  Zhu Liang; Wei Bu; Karl J Schweighofer; David J Walwark; Jeffrey S Harvey; Glenn R Hanlon; Daniel Amoanu; Cem Erol; Ilan Benjamin; Mark L Schlossman
Journal:  Proc Natl Acad Sci U S A       Date:  2018-03-12       Impact factor: 11.205

2.  On the mechanisms of ion adsorption to aqueous interfaces: air-water vs. oil-water.

Authors:  Shane W Devlin; Ilan Benjamin; Richard J Saykally
Journal:  Proc Natl Acad Sci U S A       Date:  2022-10-10       Impact factor: 12.779

Review 3.  Multiphase Microreactors Based on Liquid-Liquid and Gas-Liquid Dispersions Stabilized by Colloidal Catalytic Particles.

Authors:  Dmytro Dedovets; Qingyuan Li; Loïc Leclercq; Veronique Nardello-Rataj; Jacques Leng; Shuangliang Zhao; Marc Pera-Titus
Journal:  Angew Chem Int Ed Engl       Date:  2021-10-01       Impact factor: 16.823
  3 in total

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