Literature DB >> 25492381

Protecting metal-organic framework crystals from hydrolytic degradation by spray-dry encapsulating them into polystyrene microspheres.

Arnau Carné-Sánchez1, Kyriakos C Stylianou, Carlos Carbonell, Majid Naderi, Inhar Imaz, Daniel Maspoch.   

Abstract

Many metal-organic frameworks are water labile, including the iconic Hong-Kong University of Science and Technology-1 (HKUST-1). Spray-dry encapsulation of HKUST-1 crystals into polystyrene microspheres is reported here to yield composites that are resistant to water but retain most of the excellent gas sorption capacity of HKUST-1. These composites are demonstrated to exhibit superior water adsorption/desorption cycling, maintaining the level of water uptake even after three cycles.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  composites; metal-organic frameworks; organic polymers; spray-drying synthesis; water sorption

Year:  2014        PMID： 25492381      PMCID： PMC4876919          DOI： 10.1002/adma.201403827

Source DB:  PubMed          Journal:  Adv Mater        ISSN： 0935-9648            Impact factor:   30.849


  29 in total

1.  Ultrahigh porosity in metal-organic frameworks.

Authors:  Hiroyasu Furukawa; Nakeun Ko; Yong Bok Go; Naoki Aratani; Sang Beom Choi; Eunwoo Choi; A Ozgür Yazaydin; Randall Q Snurr; Michael O'Keeffe; Jaheon Kim; Omar M Yaghi
Journal:  Science       Date:  2010-07-01       Impact factor: 47.728

2.  Surface modification and functionalization of nanoscale metal-organic frameworks for controlled release and luminescence sensing.

Authors:  William J Rieter; Kathryn M L Taylor; Wenbin Lin
Journal:  J Am Chem Soc       Date:  2007-07-24       Impact factor: 15.419

3.  How can a hydrophobic MOF be water-unstable? Insight into the hydration mechanism of IRMOFs.

Authors:  Marta De Toni; Romain Jonchiere; Pluton Pullumbi; François-Xavier Coudert; Alain H Fuchs
Journal:  Chemphyschem       Date:  2012-07-20       Impact factor: 3.102

4.  Hydrocarbon separations in a metal-organic framework with open iron(II) coordination sites.

Authors:  Eric D Bloch; Wendy L Queen; Rajamani Krishna; Joseph M Zadrozny; Craig M Brown; Jeffrey R Long
Journal:  Science       Date:  2012-03-30       Impact factor: 47.728

5.  Water adsorption in porous metal-organic frameworks and related materials.

Authors:  Hiroyasu Furukawa; Felipe Gándara; Yue-Biao Zhang; Juncong Jiang; Wendy L Queen; Matthew R Hudson; Omar M Yaghi
Journal:  J Am Chem Soc       Date:  2014-03-11       Impact factor: 15.419

6.  On the mechanism behind the instability of isoreticular metal-organic frameworks (IRMOFs) in humid environments.

Authors:  Luca Bellarosa; Juan Manuel Castillo; Thijs Vlugt; Sofía Calero; Núria López
Journal:  Chemistry       Date:  2012-08-21       Impact factor: 5.236

7.  Methane storage in metal-organic frameworks: current records, surprise findings, and challenges.

Authors:  Yang Peng; Vaiva Krungleviciute; Ibrahim Eryazici; Joseph T Hupp; Omar K Farha; Taner Yildirim
Journal:  J Am Chem Soc       Date:  2013-07-26       Impact factor: 15.419

8.  Adjusting the stability of metal-organic frameworks under humid conditions by ligand functionalization.

Authors:  Himanshu Jasuja; You-gui Huang; Krista S Walton
Journal:  Langmuir       Date:  2012-11-28       Impact factor: 3.882

9.  Scalable room-temperature conversion of copper(II) hydroxide into HKUST-1 (Cu3 (btc)2).

Authors:  Gerardo Majano; Javier Pérez-Ramírez
Journal:  Adv Mater       Date:  2012-11-29       Impact factor: 30.849

10.  Molecular decoding using luminescence from an entangled porous framework.

Authors:  Yohei Takashima; Virginia Martínez Martínez; Shuhei Furukawa; Mio Kondo; Satoru Shimomura; Hiromitsu Uehara; Masashi Nakahama; Kunihisa Sugimoto; Susumu Kitagawa
Journal:  Nat Commun       Date:  2011-01-25       Impact factor: 14.919
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  5 in total

1.  Imparting amphiphobicity on single-crystalline porous materials.

Authors:  Qi Sun; Hongming He; Wen-Yang Gao; Briana Aguila; Lukasz Wojtas; Zhifeng Dai; Jixue Li; Yu-Sheng Chen; Feng-Shou Xiao; Shengqian Ma
Journal:  Nat Commun       Date:  2016-10-31       Impact factor: 14.919

2.  Facile stabilization of a cyclodextrin metal-organic framework under humid environment via hydrogen sulfide treatment.

Authors:  Duo Ke; Jun-Feng Feng; Di Wu; Jun-Bo Hou; Xiao-Qin Zhang; Bang-Jing Li; Sheng Zhang
Journal:  RSC Adv       Date:  2019-06-11       Impact factor: 4.036

3.  Tailor-made synthesis of an melamine-based aminal hydrophobic polymer for selective adsorption of toxic organic pollutants: an initiative towards wastewater purification.

Authors:  Debanjan Dey; Naresh Chandra Murmu; Priyabrata Banerjee
Journal:  RSC Adv       Date:  2019-03-06       Impact factor: 4.036

Review 4.  Performance of metal-organic frameworks for the adsorptive removal of potentially toxic elements in a water system: a critical review.

Authors:  Sammani Ramanayaka; Meththika Vithanage; Ajit Sarmah; Taicheng An; Ki-Hyun Kim; Yong Sik Ok
Journal:  RSC Adv       Date:  2019-10-24       Impact factor: 4.036

Review 5.  Improving MOF stability: approaches and applications.

Authors:  Meili Ding; Xuechao Cai; Hai-Long Jiang
Journal:  Chem Sci       Date:  2019-10-02       Impact factor: 9.825
  5 in total

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