Literature DB >> 25484783

Crystal structure of poly[[{μ2-1,4-bis[(1H-imid-azol-1-yl)methyl]benzene}[μ6-5-(4-carboxylatophenoxy)isophthalato]-μ3-hydroxido-dicobalt(II)] 0.25-hydrate].

Yaping Li1, Dajun Sun2, Julia Ming3, Liying Han4, Guanfang Su1.   

Abstract

The title coordination polymer, {[Co2(C15H7O7)(OH)(C14H14N4)]·0.25H2O} n , was synthesized under hydro-thermal conditions. The asymmetric unit contains two Co(2+) ions, one L (3-) anion originating from 5-(4-carb-oxy-phen-oxy)isophthalic acid (H3 L), one OH(-) ligand, one 1,4-bis-[(1H-imidazol-l-yl)meth-yl]benzene (bix) ligand and one disordered lattice water mol-ecule (occupancy 0.25). The two Co(2+) ions have different environments. One has an octa-hedral O4N2 coordin-ation sphere, defined by four O atoms from three carboxyl-ate groups and one OH(-) ligand, and two N atoms from two symmetry-related bix ligands. The other has a trigonal-bipyramidal O5 coordination sphere resulting from three carboxyl-ate groups and two OH(-) ligands. The dihedral angles between the two benzene rings in the L (3-) ligand and between the benzene ring and the two imidazole rings in the bix ligand are 67.05 (15), 75.27 (17) and 82.05 (17)°, respectively. Four neighbouring Co(2+) ions are linked by six carboxyl-ate groups and two μ 3-OH ligands, forming a butterfly-shaped secondary building unit (SBU). These SBUs are connected by L (3-) anions into layers parallel to (1-10). Adjacent layers are cross-linked by the bix ligands, forming a three-dimensional framework that has a bimodal (3,8)-connected tfz-d topology. The disordered lattice water mol-ecule is located in the voids of the framework and has O⋯O and O⋯N contacts of 2.81 (2) and 2.95 (2) Å, suggesting medium-strength hydrogen bonds. The title compound may be a good candidate for artificial eye lenses.

Entities:  

Keywords:  (3,8)-connected tfz-d topology; CoII complex; crystal structure

Year:  2014        PMID： 25484783      PMCID： PMC4257313          DOI： 10.1107/S1600536814022806

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For general background to the properties and applications of compounds with metal-organic framework structures (MOFs), see: Batten & Robson (1998 ▶); Farrusseng et al. (2009 ▶); Iremonger et al. (2013 ▶); Kreno et al. (2012 ▶); Kurmoo (2009 ▶); Song et al. (2013 ▶); Su et al. (2012 ▶); Wong et al. (2006 ▶). For topological analysis of crystal structures, see: Blatov et al. (2010 ▶).

Experimental

Crystal data

[Co2(C15H7O7)(OH)(C14H14N4)]·0.25H2O M = 676.87 Triclinic, a = 10.7381 (6) Å b = 10.7477 (6) Å c = 13.5585 (12) Å α = 95.596 (1)° β = 91.497 (1)° γ = 118.728 (1)° V = 1360.85 (16) Å3 Z = 2 Mo Kα radiation μ = 1.28 mm−1 T = 173 K 0.19 × 0.16 × 0.15 mm

Data collection

Bruker APEXII CCD diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2010 ▶) T min = 0.793, T max = 0.831 7626 measured reflections 5314 independent reflections 4359 reflections with I > 2σ(I) R int = 0.024

Refinement

R[F 2 > 2σ(F 2)] = 0.037 wR(F 2) = 0.086 S = 1.04 5314 reflections 396 parameters 1 restraint H atoms treated by a mixture of independent and constrained refinement Δρmax = 0.37 e Å−3 Δρmin = −0.37 e Å−3

Data collection: APEX2 (Bruker, 2010 ▶); cell refinement: SAINT (Bruker, 2010 ▶); data reduction: SAINT (Bruker, 2010 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: XP in SHELXTL (Sheldrick, 2008 ▶) and DIAMOND (Brandenburg & Putz, 2010 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶). Crystal structure: contains datablock(s) I, New_Global_Publ_Block. DOI: 10.1107/S1600536814022806/wm5040sup1.cif Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536814022806/wm5040Isup2.hkl Click here for additional data file. x y z x y z x y z x y z x y z . DOI: 10.1107/S1600536814022806/wm5040fig1.tif The extended asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. The disordered lattice water mol­ecule has been omitted for clarity. [Symmetry codes: i) 2 − x, 2 − y, 1 − z; ii) 2 − x, 1 − y, 1 − z; iii) −1 + x, −1 + y, z; iv) 2 − x, 2 − y, −z; v) 1 − x, 1 − y, z.] Click here for additional data file. x y z . DOI: 10.1107/S1600536814022806/wm5040fig2.tif The tetra­nuclear SBU in the structure of the title compound. [Symmetry code: A) 1 − x,1 − y,-z.] Click here for additional data file. L 3− . DOI: 10.1107/S1600536814022806/wm5040fig3.tif View of the layered network formed by the SBUs and the L 3− anions. CCDC reference: 1029647 Additional supporting information: crystallographic information; 3D view; checkCIF report
[Co2(C15H7O7)(OH)(C14H14N4)]·0.25H2OV = 1360.85 (16) Å3
Mr = 676.87Z = 2
Triclinic, P1F(000) = 688
Hall symbol: -P 1Dx = 1.651 Mg m−3
a = 10.7381 (6) ÅMo Kα radiation, λ = 0.71073 Å
b = 10.7477 (6) ŵ = 1.28 mm−1
c = 13.5585 (12) ÅT = 173 K
α = 95.596 (1)°Block, red
β = 91.497 (1)°0.19 × 0.16 × 0.15 mm
γ = 118.728 (1)°
Bruker APEXII CCD diffractometer5314 independent reflections
Radiation source: fine-focus sealed tube4359 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.024
φ and ω scansθmax = 26.1°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Bruker, 2010)h = −13→7
Tmin = 0.793, Tmax = 0.831k = −12→13
7626 measured reflectionsl = −16→15
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.037Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.086H atoms treated by a mixture of independent and constrained refinement
S = 1.04w = 1/[σ2(Fo2) + (0.038P)2 + 0.1129P] where P = (Fo2 + 2Fc2)/3
5314 reflections(Δ/σ)max = 0.001
396 parametersΔρmax = 0.37 e Å−3
1 restraintΔρmin = −0.37 e Å−3
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/UeqOcc. (<1)
C41.2218 (3)0.9155 (3)0.33134 (18)0.0184 (6)
C51.3041 (3)1.0414 (3)0.29083 (18)0.0174 (6)
H51.39041.11450.32550.021*
C61.2583 (3)1.0586 (3)0.19865 (18)0.0142 (5)
C71.1319 (3)0.9514 (3)0.14908 (18)0.0149 (5)
H71.09970.96450.08700.018*
C81.3462 (3)1.1946 (3)0.15375 (18)0.0159 (5)
C91.2867 (3)0.9886 (3)0.50570 (18)0.0189 (6)
C101.2320 (3)1.0822 (3)0.5104 (2)0.0260 (6)
H101.17581.08280.45530.031*
C111.2605 (3)1.1752 (3)0.5968 (2)0.0235 (6)
H111.22481.24090.59980.028*
C121.3400 (3)1.1742 (3)0.67892 (19)0.0191 (6)
C131.3897 (3)1.0762 (3)0.67393 (19)0.0217 (6)
H131.44131.07200.73030.026*
C141.3646 (3)0.9841 (3)0.58730 (19)0.0217 (6)
H141.40050.91860.58390.026*
C151.3742 (3)1.2825 (3)0.76871 (19)0.0186 (6)
C160.8332 (3)0.2942 (3)0.1162 (2)0.0271 (7)
H160.91600.38560.12450.033*
C170.6168 (3)0.1286 (3)0.0961 (2)0.0338 (7)
H170.51570.08030.08780.041*
C180.6975 (3)0.0639 (3)0.0971 (2)0.0339 (7)
H180.6645−0.03610.08970.041*
C190.9626 (3)0.1515 (3)0.1249 (2)0.0323 (7)
H19A1.00800.15860.06160.039*
H19B0.93340.05540.14440.039*
C201.0678 (3)0.2645 (3)0.2043 (2)0.0287 (7)
C211.1660 (3)0.3964 (4)0.1793 (2)0.0356 (8)
H211.17180.41140.11130.043*
C221.2558 (3)0.5068 (4)0.2509 (2)0.0343 (8)
H221.32030.59750.23210.041*
C231.2520 (3)0.4855 (3)0.3500 (2)0.0281 (7)
C241.1572 (3)0.3524 (3)0.3759 (2)0.0342 (8)
H241.15570.33600.44350.041*
C251.0645 (3)0.2427 (3)0.3038 (2)0.0345 (7)
H250.99860.15260.32260.041*
C261.3528 (3)0.6094 (3)0.4265 (2)0.0342 (8)
H26A1.44520.61020.43240.041*
H26B1.37010.70020.40290.041*
C271.3559 (3)0.5860 (3)0.6085 (2)0.0255 (6)
H271.44090.57940.61270.031*
C281.1671 (3)0.5928 (3)0.6463 (2)0.0288 (7)
H281.09270.59130.68350.035*
C291.1776 (3)0.6075 (3)0.5482 (2)0.0315 (7)
H291.11410.61900.50470.038*
N31.2798 (2)0.5803 (2)0.68379 (16)0.0221 (5)
N41.2985 (3)0.6023 (3)0.52460 (17)0.0277 (6)
O31.30271 (18)1.19794 (18)0.06670 (12)0.0196 (4)
O41.45267 (18)1.29275 (18)0.20484 (13)0.0215 (4)
O51.2654 (2)0.89221 (18)0.42257 (12)0.0223 (4)
O61.4105 (2)1.25737 (19)0.85136 (13)0.0226 (4)
O71.3637 (2)1.39052 (19)0.75613 (13)0.0248 (4)
O80.58483 (19)0.45012 (18)0.02893 (13)0.0166 (4)
O1W1.333 (2)0.746 (2)0.1092 (16)0.165 (8)*0.25
H8O0.632 (3)0.422 (3)−0.0057 (19)0.030 (9)*
C10.9122 (3)0.7102 (3)0.13668 (18)0.0178 (6)
C21.0516 (3)0.8247 (3)0.18914 (18)0.0164 (5)
C31.0979 (3)0.8066 (3)0.28083 (19)0.0186 (6)
H31.04450.72000.30850.022*
N10.7019 (2)0.2740 (2)0.10884 (17)0.0235 (5)
N20.8355 (2)0.1701 (2)0.11079 (16)0.0225 (5)
O10.86795 (18)0.58516 (18)0.15727 (14)0.0230 (4)
O20.84879 (19)0.74906 (19)0.07745 (13)0.0236 (4)
Co10.65561 (4)0.43648 (3)0.16976 (2)0.01604 (10)
Co20.63498 (4)0.65449 (3)0.02558 (2)0.01564 (10)
U11U22U33U12U13U23
C40.0237 (14)0.0168 (13)0.0139 (13)0.0096 (12)−0.0039 (11)0.0018 (11)
C50.0176 (13)0.0149 (13)0.0162 (13)0.0058 (11)−0.0041 (11)−0.0010 (10)
C60.0146 (13)0.0114 (12)0.0153 (13)0.0053 (10)0.0013 (10)0.0016 (10)
C70.0168 (13)0.0147 (13)0.0134 (12)0.0080 (11)−0.0032 (10)0.0016 (10)
C80.0151 (13)0.0157 (13)0.0169 (13)0.0077 (11)−0.0019 (11)0.0019 (11)
C90.0240 (14)0.0160 (13)0.0120 (13)0.0065 (12)−0.0025 (11)0.0009 (10)
C100.0348 (17)0.0297 (16)0.0174 (14)0.0195 (14)−0.0073 (12)0.0004 (12)
C110.0288 (16)0.0224 (15)0.0230 (14)0.0159 (13)−0.0035 (12)0.0021 (12)
C120.0225 (14)0.0146 (13)0.0156 (13)0.0054 (11)−0.0009 (11)0.0024 (11)
C130.0248 (15)0.0229 (15)0.0165 (13)0.0111 (12)−0.0050 (11)0.0027 (11)
C140.0299 (16)0.0211 (14)0.0171 (14)0.0155 (13)−0.0063 (12)0.0006 (11)
C150.0163 (13)0.0167 (14)0.0185 (14)0.0045 (11)0.0002 (11)0.0035 (11)
C160.0248 (16)0.0171 (14)0.0359 (17)0.0082 (13)−0.0020 (13)−0.0008 (13)
C170.0245 (16)0.0193 (15)0.051 (2)0.0075 (13)0.0014 (14)−0.0042 (14)
C180.0354 (18)0.0161 (15)0.047 (2)0.0097 (14)0.0055 (15)0.0023 (14)
C190.0388 (18)0.0387 (18)0.0306 (17)0.0297 (16)−0.0061 (14)−0.0051 (14)
C200.0317 (17)0.0363 (18)0.0267 (16)0.0252 (15)−0.0032 (13)−0.0060 (13)
C210.0322 (18)0.060 (2)0.0190 (15)0.0266 (17)0.0005 (13)0.0028 (15)
C220.0253 (17)0.044 (2)0.0289 (17)0.0129 (15)0.0007 (13)0.0078 (15)
C230.0265 (16)0.0365 (18)0.0230 (15)0.0165 (14)0.0007 (12)0.0045 (13)
C240.046 (2)0.0370 (18)0.0225 (16)0.0226 (16)−0.0071 (14)0.0034 (14)
C250.044 (2)0.0308 (17)0.0320 (17)0.0221 (16)−0.0051 (15)0.0015 (14)
C260.0279 (17)0.0392 (19)0.0248 (16)0.0075 (15)−0.0015 (13)0.0070 (14)
C270.0231 (15)0.0245 (15)0.0243 (15)0.0087 (13)−0.0089 (12)0.0015 (12)
C280.0274 (16)0.0282 (16)0.0300 (16)0.0126 (14)−0.0033 (13)0.0064 (13)
C290.0261 (16)0.0342 (18)0.0313 (17)0.0121 (14)−0.0063 (13)0.0083 (14)
N30.0227 (13)0.0186 (12)0.0223 (12)0.0084 (10)−0.0047 (10)0.0019 (10)
N40.0277 (14)0.0245 (13)0.0230 (13)0.0066 (11)−0.0042 (10)0.0035 (10)
O30.0197 (10)0.0154 (9)0.0169 (9)0.0028 (8)−0.0040 (8)0.0057 (8)
O40.0186 (10)0.0165 (10)0.0182 (9)0.0000 (8)−0.0043 (8)0.0018 (8)
O50.0359 (12)0.0168 (10)0.0123 (9)0.0119 (9)−0.0070 (8)0.0007 (7)
O60.0324 (11)0.0194 (10)0.0159 (9)0.0133 (9)−0.0044 (8)−0.0009 (8)
O70.0352 (12)0.0159 (10)0.0236 (10)0.0131 (9)−0.0012 (9)0.0006 (8)
O80.0170 (10)0.0111 (9)0.0185 (9)0.0046 (8)−0.0016 (8)0.0006 (7)
C10.0170 (13)0.0163 (14)0.0152 (13)0.0042 (11)0.0010 (11)0.0027 (11)
C20.0172 (13)0.0141 (13)0.0160 (13)0.0062 (11)0.0000 (11)0.0018 (10)
C30.0218 (14)0.0137 (13)0.0182 (13)0.0069 (11)−0.0001 (11)0.0033 (11)
N10.0225 (12)0.0168 (12)0.0292 (13)0.0086 (10)−0.0038 (10)0.0005 (10)
N20.0278 (13)0.0208 (12)0.0219 (12)0.0155 (11)−0.0028 (10)−0.0028 (10)
O10.0160 (10)0.0139 (9)0.0337 (11)0.0030 (8)−0.0038 (8)0.0049 (8)
O20.0169 (10)0.0174 (10)0.0257 (10)−0.0009 (8)−0.0063 (8)0.0079 (8)
Co10.01564 (19)0.01004 (18)0.01836 (19)0.00323 (15)−0.00388 (14)0.00201 (14)
Co20.01722 (19)0.01009 (18)0.01444 (18)0.00264 (15)−0.00307 (14)0.00217 (14)
C4—C31.381 (4)C22—C231.383 (4)
C4—C51.391 (3)C22—H220.9500
C4—O51.398 (3)C23—C241.386 (4)
C5—C61.393 (3)C23—C261.519 (4)
C5—H50.9500C24—C251.390 (4)
C6—C71.386 (3)C24—H240.9500
C6—C81.508 (3)C25—H250.9500
C7—C21.390 (3)C26—N41.460 (4)
C7—H70.9500C26—H26A0.9900
C8—O41.248 (3)C26—H26B0.9900
C8—O31.268 (3)C27—N31.312 (4)
C9—C101.385 (4)C27—N41.346 (3)
C9—C141.388 (3)C27—H270.9500
C9—O51.388 (3)C28—C291.357 (4)
C10—C111.386 (4)C28—N31.371 (3)
C10—H100.9500C28—H280.9500
C11—C121.390 (3)C29—N41.370 (4)
C11—H110.9500C29—H290.9500
C12—C131.388 (4)N3—Co1i2.139 (2)
C12—C151.504 (4)O3—Co2ii1.9848 (16)
C13—C141.390 (4)O4—Co1iii2.0791 (17)
C13—H130.9500O6—Co2iv2.0247 (18)
C14—H140.9500O7—Co1iv2.1279 (19)
C15—O71.246 (3)O8—Co22.0000 (17)
C15—O61.272 (3)O8—Co12.0811 (17)
C16—N11.318 (4)O8—Co2v2.1395 (18)
C16—N21.341 (3)O8—H8O0.839 (17)
C16—H160.9500C1—O11.256 (3)
C17—C181.347 (4)C1—O21.262 (3)
C17—N11.369 (4)C1—C21.505 (3)
C17—H170.9500C2—C31.392 (3)
C18—N21.360 (4)C3—H30.9500
C18—H180.9500N1—Co12.134 (2)
C19—N21.482 (3)O1—Co12.0860 (17)
C19—C201.508 (4)O2—Co22.0813 (18)
C19—H19A0.9900Co1—O4vi2.0791 (17)
C19—H19B0.9900Co1—O7iv2.1279 (19)
C20—C211.383 (4)Co1—N3i2.139 (2)
C20—C251.390 (4)Co2—O3ii1.9848 (16)
C21—C221.381 (4)Co2—O6iv2.0247 (18)
C21—H210.9500Co2—O8v2.1395 (18)
C3—C4—C5121.2 (2)N4—C26—H26B108.9
C3—C4—O5117.7 (2)C23—C26—H26B108.9
C5—C4—O5120.9 (2)H26A—C26—H26B107.8
C4—C5—C6119.0 (2)N3—C27—N4111.6 (3)
C4—C5—H5120.5N3—C27—H27124.2
C6—C5—H5120.5N4—C27—H27124.2
C7—C6—C5119.9 (2)C29—C28—N3109.8 (3)
C7—C6—C8120.4 (2)C29—C28—H28125.1
C5—C6—C8119.7 (2)N3—C28—H28125.1
C6—C7—C2120.7 (2)C28—C29—N4106.0 (3)
C6—C7—H7119.6C28—C29—H29127.0
C2—C7—H7119.6N4—C29—H29127.0
O4—C8—O3126.2 (2)C27—N3—C28105.6 (2)
O4—C8—C6118.0 (2)C27—N3—Co1i121.73 (19)
O3—C8—C6115.9 (2)C28—N3—Co1i132.6 (2)
C10—C9—C14120.6 (2)C27—N4—C29107.0 (2)
C10—C9—O5123.5 (2)C27—N4—C26126.5 (3)
C14—C9—O5115.8 (2)C29—N4—C26126.5 (2)
C9—C10—C11119.0 (2)C8—O3—Co2ii134.31 (16)
C9—C10—H10120.5C8—O4—Co1iii132.65 (17)
C11—C10—H10120.5C9—O5—C4118.20 (19)
C10—C11—C12121.4 (3)C15—O6—Co2iv115.77 (17)
C10—C11—H11119.3C15—O7—Co1iv144.04 (18)
C12—C11—H11119.3Co2—O8—Co1106.75 (8)
C13—C12—C11118.7 (2)Co2—O8—Co2v100.27 (8)
C13—C12—C15122.1 (2)Co1—O8—Co2v123.61 (8)
C11—C12—C15119.2 (2)Co2—O8—H8O116 (2)
C12—C13—C14120.7 (2)Co1—O8—H8O99 (2)
C12—C13—H13119.7Co2v—O8—H8O112 (2)
C14—C13—H13119.7O1—C1—O2125.9 (2)
C9—C14—C13119.5 (3)O1—C1—C2117.1 (2)
C9—C14—H14120.2O2—C1—C2117.0 (2)
C13—C14—H14120.2C7—C2—C3119.5 (2)
O7—C15—O6124.9 (2)C7—C2—C1120.6 (2)
O7—C15—C12116.9 (2)C3—C2—C1119.8 (2)
O6—C15—C12118.2 (2)C4—C3—C2119.6 (2)
N1—C16—N2111.8 (2)C4—C3—H3120.2
N1—C16—H16124.1C2—C3—H3120.2
N2—C16—H16124.1C16—N1—C17104.8 (2)
C18—C17—N1110.1 (3)C16—N1—Co1120.66 (19)
C18—C17—H17125.0C17—N1—Co1129.3 (2)
N1—C17—H17125.0C16—N2—C18106.8 (2)
C17—C18—N2106.5 (2)C16—N2—C19126.8 (2)
C17—C18—H18126.8C18—N2—C19126.2 (2)
N2—C18—H18126.8C1—O1—Co1125.59 (17)
N2—C19—C20110.2 (2)C1—O2—Co2130.90 (16)
N2—C19—H19A109.6O4vi—Co1—O893.75 (7)
C20—C19—H19A109.6O4vi—Co1—O1171.43 (7)
N2—C19—H19B109.6O8—Co1—O194.52 (7)
C20—C19—H19B109.6O4vi—Co1—O7iv90.30 (7)
H19A—C19—H19B108.1O8—Co1—O7iv95.87 (7)
C21—C20—C25118.4 (3)O1—Co1—O7iv86.61 (7)
C21—C20—C19119.7 (3)O4vi—Co1—N194.34 (8)
C25—C20—C19121.7 (3)O8—Co1—N190.45 (8)
C22—C21—C20121.5 (3)O1—Co1—N187.85 (8)
C22—C21—H21119.2O7iv—Co1—N1171.91 (8)
C20—C21—H21119.2O4vi—Co1—N3i84.20 (8)
C21—C22—C23120.0 (3)O8—Co1—N3i177.78 (8)
C21—C22—H22120.0O1—Co1—N3i87.50 (8)
C23—C22—H22120.0O7iv—Co1—N3i83.32 (8)
C22—C23—C24119.1 (3)N1—Co1—N3i90.55 (9)
C22—C23—C26118.5 (3)O3ii—Co2—O8140.83 (8)
C24—C23—C26122.5 (3)O3ii—Co2—O6iv104.88 (7)
C23—C24—C25120.7 (3)O8—Co2—O6iv113.82 (7)
C23—C24—H24119.7O3ii—Co2—O286.27 (7)
C25—C24—H24119.7O8—Co2—O298.24 (7)
C20—C25—C24120.2 (3)O6iv—Co2—O291.54 (8)
C20—C25—H25119.9O3ii—Co2—O8v94.91 (7)
C24—C25—H25119.9O8—Co2—O8v79.73 (8)
N4—C26—C23113.2 (2)O6iv—Co2—O8v89.87 (7)
N4—C26—H26A108.9O2—Co2—O8v177.87 (7)
C23—C26—H26A108.9
C3—C4—C5—C61.6 (4)C6—C7—C2—C31.0 (4)
O5—C4—C5—C6178.5 (2)C6—C7—C2—C1178.1 (2)
C4—C5—C6—C70.3 (4)O1—C1—C2—C7158.0 (2)
C4—C5—C6—C8179.9 (2)O2—C1—C2—C7−23.4 (4)
C5—C6—C7—C2−1.6 (4)O1—C1—C2—C3−24.9 (4)
C8—C6—C7—C2178.8 (2)O2—C1—C2—C3153.7 (2)
C7—C6—C8—O4174.1 (2)C5—C4—C3—C2−2.2 (4)
C5—C6—C8—O4−5.5 (4)O5—C4—C3—C2−179.2 (2)
C7—C6—C8—O3−5.3 (4)C7—C2—C3—C40.9 (4)
C5—C6—C8—O3175.1 (2)C1—C2—C3—C4−176.3 (2)
C14—C9—C10—C112.3 (4)N2—C16—N1—C17−1.2 (3)
O5—C9—C10—C11−179.5 (2)N2—C16—N1—Co1155.63 (18)
C9—C10—C11—C12−1.3 (4)C18—C17—N1—C160.7 (4)
C10—C11—C12—C13−0.9 (4)C18—C17—N1—Co1−153.4 (2)
C10—C11—C12—C15176.8 (3)N1—C16—N2—C181.2 (3)
C11—C12—C13—C142.2 (4)N1—C16—N2—C19−174.3 (3)
C15—C12—C13—C14−175.4 (2)C17—C18—N2—C16−0.8 (3)
C10—C9—C14—C13−1.0 (4)C17—C18—N2—C19174.8 (3)
O5—C9—C14—C13−179.4 (2)C20—C19—N2—C1636.0 (4)
C12—C13—C14—C9−1.3 (4)C20—C19—N2—C18−138.8 (3)
C13—C12—C15—O7158.7 (3)O2—C1—O1—Co1−36.0 (4)
C11—C12—C15—O7−18.9 (4)C2—C1—O1—Co1142.50 (19)
C13—C12—C15—O6−21.7 (4)O1—C1—O2—Co221.4 (4)
C11—C12—C15—O6160.7 (2)C2—C1—O2—Co2−157.07 (18)
N1—C17—C18—N20.1 (4)Co2—O8—Co1—O4vi119.02 (9)
N2—C19—C20—C21−86.0 (3)Co2v—O8—Co1—O4vi3.95 (11)
N2—C19—C20—C2590.5 (3)Co2—O8—Co1—O1−58.72 (9)
C25—C20—C21—C22−2.4 (5)Co2v—O8—Co1—O1−173.79 (10)
C19—C20—C21—C22174.3 (3)Co2—O8—Co1—O7iv28.33 (9)
C20—C21—C22—C232.0 (5)Co2v—O8—Co1—O7iv−86.74 (11)
C21—C22—C23—C240.1 (5)Co2—O8—Co1—N1−146.60 (9)
C21—C22—C23—C26179.8 (3)Co2v—O8—Co1—N198.33 (11)
C22—C23—C24—C25−1.8 (5)Co2—O8—Co1—N3i97 (2)
C26—C23—C24—C25178.5 (3)Co2v—O8—Co1—N3i−18 (2)
C21—C20—C25—C240.7 (5)C1—O1—Co1—O4vi−109.8 (5)
C19—C20—C25—C24−175.9 (3)C1—O1—Co1—O854.9 (2)
C23—C24—C25—C201.4 (5)C1—O1—Co1—O7iv−40.8 (2)
C22—C23—C26—N4152.3 (3)C1—O1—Co1—N1145.2 (2)
C24—C23—C26—N4−28.0 (4)C1—O1—Co1—N3i−124.2 (2)
N3—C28—C29—N40.7 (3)C16—N1—Co1—O4vi−147.6 (2)
N4—C27—N3—C280.3 (3)C17—N1—Co1—O4vi2.9 (3)
N4—C27—N3—Co1i−177.40 (17)C16—N1—Co1—O8118.6 (2)
C29—C28—N3—C27−0.6 (3)C17—N1—Co1—O8−90.9 (3)
C29—C28—N3—Co1i176.76 (19)C16—N1—Co1—O124.1 (2)
N3—C27—N4—C290.1 (3)C17—N1—Co1—O1174.6 (3)
N3—C27—N4—C26−178.5 (3)C16—N1—Co1—O7iv−22.8 (7)
C28—C29—N4—C27−0.4 (3)C17—N1—Co1—O7iv127.7 (5)
C28—C29—N4—C26178.1 (3)C16—N1—Co1—N3i−63.4 (2)
C23—C26—N4—C27115.6 (3)C17—N1—Co1—N3i87.1 (3)
C23—C26—N4—C29−62.6 (4)Co1—O8—Co2—O3ii144.91 (9)
O4—C8—O3—Co2ii−3.0 (4)Co2v—O8—Co2—O3ii−85.14 (12)
C6—C8—O3—Co2ii176.27 (17)Co1—O8—Co2—O6iv−44.69 (10)
O3—C8—O4—Co1iii−39.8 (4)Co2v—O8—Co2—O6iv85.26 (9)
C6—C8—O4—Co1iii140.96 (19)Co1—O8—Co2—O250.69 (9)
C10—C9—O5—C418.1 (4)Co2v—O8—Co2—O2−179.37 (7)
C14—C9—O5—C4−163.6 (2)Co1—O8—Co2—O8v−129.95 (12)
C3—C4—O5—C9−123.9 (3)Co2v—O8—Co2—O8v0.0
C5—C4—O5—C959.1 (3)C1—O2—Co2—O3ii−171.8 (2)
O7—C15—O6—Co2iv27.6 (3)C1—O2—Co2—O8−31.0 (2)
C12—C15—O6—Co2iv−151.95 (18)C1—O2—Co2—O6iv83.4 (2)
O6—C15—O7—Co1iv−17.9 (5)C1—O2—Co2—O8v−48 (2)
C12—C15—O7—Co1iv161.6 (2)
  6 in total

Review 1.  Metal-organic framework materials as chemical sensors.

Authors:  Lauren E Kreno; Kirsty Leong; Omar K Farha; Mark Allendorf; Richard P Van Duyne; Joseph T Hupp
Journal:  Chem Rev       Date:  2011-11-09       Impact factor: 60.622

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  Magnetic metal-organic frameworks.

Authors:  Mohamedally Kurmoo
Journal:  Chem Soc Rev       Date:  2009-02-24       Impact factor: 54.564

4.  Two high-connected metal-organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties.

Authors:  Xue-Zhi Song; Shu-Yan Song; Shu-Na Zhao; Zhao-Min Hao; Min Zhu; Xing Meng; Hong-Jie Zhang
Journal:  Dalton Trans       Date:  2013-04-30       Impact factor: 4.390

5.  Zn7O2(RCOO)10 clusters and nitro aromatic linkers in a porous metal-organic framework.

Authors:  Simon S Iremonger; Ramanathan Vaidhyanathan; Roger K Mah; George K H Shimizu
Journal:  Inorg Chem       Date:  2013-03-22       Impact factor: 5.165

6.  Metal-organic frameworks: opportunities for catalysis.

Authors:  David Farrusseng; Sonia Aguado; Catherine Pinel
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336
  6 in total

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