| Literature DB >> 25484484 |
Melanie A Pribisko1, Tonia S Ahmed1, Robert H Grubbs1.
Abstract
Two new Ru-based metathesis catalysts, 3 and 4, have been synthesized for the purpose of comparing their catalytic properties to those of their cis-selective nitrate analogues, 1 and 2. Although catalysts 3 and 4 exhibited slower initiation rates than 1 and 2, they maintained high cis-selectivity in homodimerization and ring-opening metathesis polymerization reactions. Furthermore, the nitrite catalysts displayed higher cis-selectivity than 2 for ring-opening metathesis polymerizations, and 4 delivered higher yields of polymer.Entities:
Year: 2014 PMID： 25484484 PMCID： PMC4254782 DOI： 10.1016/j.poly.2014.06.055
Source DB: PubMed Journal: Polyhedron ISSN： 0277-5387 Impact factor: 3.052