| Literature DB >> 25484371 |
Liliya V Frolova1, Igor V Magedov1, Aaron Harper1, Sanjiv K Jha2, Mekan Ovezmyradov3, Gary Chandler3, Jill Garcia3, Donald Bethke4, Eric A Shaner4, Igor Vasiliev2, Nikolai G Kalugin5.
Abstract
The tetracyanoethylene oxide (TCNEO) functionalization of chemical vapor deposition grown large area graphene and graphite was performed using reaction of TCNEO with carbon surface in chlorobenzene. The successful functionalization has been confirmed by Raman and Auger spectroscopy, and by numerical modeling of the structure and vibrational modes of TCNEO-functionalized graphene. Raman spectra of TCNEO-functionalized graphene and graphite show several groups of lines corresponding to vibrations of attached carbonyl ylide. One of key signatures of TCNEO attachment is the high intensity Raman band at ~1450 cm-1, which represents the C-C=C in plane vibrations in functionalization-distorted graphene. Raman spectra indicate the existence of central (pristine) attachment of TCNEO to graphene surface.Entities:
Year: 2015 PMID： 25484371 PMCID： PMC4251559 DOI： 10.1016/j.carbon.2014.09.052
Source DB: PubMed Journal: Carbon N Y ISSN： 0008-6223 Impact factor: 9.594