Literature DB >> 25477001

Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes.

Tasuku Inami1, Takuya Kurahashi, Seijiro Matsubara.   

Abstract

The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.

Entities:  

Year:  2015        PMID: 25477001     DOI: 10.1039/c4cc09123j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Thioether-functionalized trifluoromethyl-alkynes, 1,3-dienes and allenes: divergent synthesis from reaction of 2-trifluoromethyl-1,3-conjugated enynes with sulfur nucleophiles.

Authors:  Huayu Cheng; Xiaofan Zhou; Anjing Hu; Shiteng Ding; Yimo Wang; Yuanjing Xiao; Junliang Zhang
Journal:  RSC Adv       Date:  2018-10-04       Impact factor: 4.036

  1 in total

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