Literature DB >> 25451720

The first 3-connected SrSi2 -type 3D chiral framework constructed from {Ni6 PW9 } building units.

Xin-Xiong Li1, Wei-Hui Fang, Jun-Wei Zhao, Guo-Yu Yang.   

Abstract

A novel 3-connected SrSi2 -type 3D chiral framework constructed from hexa-Ni(II) -cluster-substituted polyoxometalate (POM) units [Ni(enMe)2 ]3 [WO4 ]3 [Ni6 (enMe)3 (OH)3 PW9 O34 ]2 ⋅9H2 O (1) (enMe=1,2-diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on {Ni6 PW9 } units and {WO4 } connectors.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  chiral framework; cluster compounds; nickel; polyoxometalate

Year:  2014        PMID: 25451720     DOI: 10.1002/chem.201405290

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  1 in total

1.  Designed Syntheses of Three {Ni6PW9}-Based Polyoxometalates, from Isolated Cluster to Cluster-Organic Helical Chain.

Authors:  Chong-An Chen; Yan Liu; Guo-Yu Yang
Journal:  Molecules       Date:  2022-07-04       Impact factor: 4.927

  1 in total

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