Literature DB >> 25434744

Isoselective 3,4-(co)polymerization of bio-renewable myrcene using NSN-ligated rare-earth metal precursor: an approach to a new elastomer.

Bo Liu1, Lei Li, Guangping Sun, Dongtao Liu, Shihui Li, Dongmei Cui.   

Abstract

The polymerization of bio-renewable myrcene (MY), using a cationic β-diimidosulfonate lutetium catalyst in high activity, afforded an unprecedented isotactic 3,4-polymyrcene (PMY) with a low Tg (-42 °C). Based on this result, the random and block copolymerization of myrcene and isoprene (IP) resulted in novel elastomers that comprise the amorphous iso-3,4-PMY and iso-3,4-PIP sequences.

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Year:  2015        PMID: 25434744     DOI: 10.1039/c4cc08962f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Polymerization of Myrcene in Both Conventional and Renewable Solvents: Postpolymerization Modification via Regioselective Photoinduced Thiol-Ene Chemistry for Use as Carbon Renewable Dispersants.

Authors:  Jirui Zhang; Cansu Aydogan; Georgios Patias; Timothy Smith; Lucas Al-Shok; Huizhe Liu; Ahmed M Eissa; David M Haddleton
Journal:  ACS Sustain Chem Eng       Date:  2022-07-11       Impact factor: 9.224

2.  Controlled, one-pot synthesis of recyclable poly(1,3-diene)-polyester block copolymers, catalyzed by yttrium β-diketiminate complexes.

Authors:  Sophia C Kosloski-Oh; Yvonne Manjarrez; Taleen J Boghossian; Megan E Fieser
Journal:  Chem Sci       Date:  2022-08-08       Impact factor: 9.969

3.  Coordinative Chain Transfer Polymerization of Sustainable Terpene Monomers Using a Neodymium-Based Catalyst System.

Authors:  Teresa Córdova; Francisco Javier Enríquez-Medrano; Eduardo Martínez Cartagena; Arnulfo Banda Villanueva; Luis Valencia; Edgar Nazareo Cabrera Álvarez; Ricardo López González; Ramón Díaz-de-León
Journal:  Polymers (Basel)       Date:  2022-07-17       Impact factor: 4.967

4.  Renewable Beta-Elemene Based Cyclic Carbonates for the Preparation of Oligo(hydroxyurethane)s.

Authors:  Cristina Maquilón; Arianna Brandolese; Christian Alter; Claas H Hövelmann; Francesco Della Monica; Arjan W Kleij
Journal:  ChemSusChem       Date:  2022-07-25       Impact factor: 9.140

  4 in total

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