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Literature DB >> 25431812

Intramolecular hydroalkoxylation catalyzed inside a self-assembled cavity of an enzyme-like host structure.

Abstract

Self-assembled resorcin[4]arene hexamer catalyzes the intramolecular hydroalkoxylation of unsaturated alcohols to the corresponding cyclic ethers under mild conditions. The mode of catalysis and encapsulation-based substrate selectivity of the host efficiently mimic the basic principle of operation observed in enzymes.

Entities: Chemical

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Year: 2015 PMID： 25431812 DOI： 10.1039/c4cc08211g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.

Authors: Trandon A Bender; Robert G Bergman; Kenneth N Raymond; F Dean Toste
Journal: J Am Chem Soc Date: 2019-07-16 Impact factor: 15.419

2. To catalyze or not to catalyze: elucidation of the subtle differences between the hexameric capsules of pyrogallolarene and resorcinarene.

Authors: Qi Zhang; Lorenzo Catti; Ville R I Kaila; Konrad Tiefenbacher
Journal: Chem Sci Date: 2016-11-15 Impact factor: 9.825

Intramolecular hydroalkoxylation catalyzed inside a self-assembled cavity of an enzyme-like host structure.

1. A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.

2. To catalyze or not to catalyze: elucidation of the subtle differences between the hexameric capsules of pyrogallolarene and resorcinarene.

Review 3. Catalytic Asymmetric Hydroalkoxylation of C-C Multiple Bonds.

4. A resorcin[4]arene hexameric capsule as a supramolecular catalyst in elimination and isomerization reactions.

5. Biomimetic Total Synthesis and Investigation of the Non-Enzymatic Chemistry of Oxazinin A.

6. Bioinspired synthesis of pentacyclic onocerane triterpenoids.

7. Size-Selective Hydroformylation by a Rhodium Catalyst Confined in a Supramolecular Cage.