Literature DB >> 25426822

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau.

David J Harding1, Wasinee Phonsri, Phimphaka Harding, Keith S Murray, Boujemaa Moubaraki, Guy N L Jameson.   

Abstract

[Fe(qsal-Br)2]NO3·2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T½(1st step) = 136 K and T½(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.

Entities:  

Year:  2015        PMID： 25426822     DOI： 10.1039/c4dt03184a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis.

Authors:  Wasinee Phonsri; Phimphaka Harding; Lujia Liu; Shane G Telfer; Keith S Murray; Boujemaa Moubaraki; Tamsyn M Ross; Guy N L Jameson; David J Harding
Journal:  Chem Sci       Date:  2017-03-23       Impact factor: 9.825

2.  Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling.

Authors:  Vibe Boel Jakobsen; Elzbieta Trzop; Emiel Dobbelaar; Laurence C Gavin; Shalinee Chikara; Xiaxin Ding; Minseong Lee; Kane Esien; Helge Müller-Bunz; Solveig Felton; Eric Collet; Michael A Carpenter; Vivien S Zapf; Grace G Morgan
Journal:  J Am Chem Soc       Date:  2021-12-23       Impact factor: 15.419

3.  An Incomplete Spin Transition Associated with a Z'=1→Z'=24 Crystallographic Symmetry Breaking.

Authors:  Izar Capel Berdiell; Rafal Kulmaczewski; Oscar Cespedes; Malcolm A Halcrow
Journal:  Chemistry       Date:  2017-11-22       Impact factor: 5.236
  3 in total

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