| Literature DB >> 25418863 |
Wouter Debrouwer1, Ruben A J Seigneur, Thomas S A Heugebaert, Christian V Stevens.
Abstract
A three-step synthesis of benzo[c]thiophenes is presented in which the key transformation is the gold-catalyzed 5-exo-dig migratory cycloisomerization of a diallyl thioacetal. It was shown that a small amount of in situ generated HAuCl4 from AuCl3 is the active catalytic species. A mechanism was proposed.Entities:
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Year: 2014 PMID： 25418863 DOI： 10.1039/c4cc07989b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222