Literature DB >> 25414056

Stereospecific couplings of secondary and tertiary boronic esters.

Daniele Leonori1, Varinder K Aggarwal.   

Abstract

This Minireview highlights advances in the Suzuki-Miyaura cross-coupling of secondary boron reagents for the creation of C-C bonds with control of stereochemistry. It also includes non-transition-metal coupling of secondary and tertiary boronic esters to electron-rich aromatics.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  boron; cross-coupling; homogeneous catalysis; palladium; synthetic methods

Year:  2014        PMID： 25414056     DOI： 10.1002/anie.201407701

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  48 in total

1.  Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.

Authors:  Gia L Hoang; Zhao-Di Yang; Sean M Smith; Rhitankar Pal; Judy L Miska; Damaris E Pérez; Libbie S W Pelter; Xiao Cheng Zeng; James M Takacs
Journal:  Org Lett       Date:  2015-02-02       Impact factor: 6.005

2.  Benzyltriboronates: Building Blocks for Diastereoselective Carbon-Carbon Bond Formation.

Authors:  W Neil Palmer; Cayetana Zarate; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2017-02-13       Impact factor: 15.419

3.  Genetically programmed chiral organoborane synthesis.

Authors:  S B Jennifer Kan; Xiongyi Huang; Yosephine Gumulya; Kai Chen; Frances H Arnold
Journal:  Nature       Date:  2017-11-29       Impact factor: 49.962

4.  Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis.

Authors:  Gregory L Lackner; Kyle W Quasdorf; Gerald Pratsch; Larry E Overman
Journal:  J Org Chem       Date:  2015-06-01       Impact factor: 4.354

5.  Stereospecific Palladium-Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions.

Authors:  Chao-Yuan Wang; Glenn Ralph; Joseph Derosa; Mark R Biscoe
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-16       Impact factor: 15.336

6.  Diversity-Oriented Enzymatic Synthesis of Cyclopropane Building Blocks.

Authors:  Bruce J Wittmann; Anders M Knight; Julie L Hofstra; Sarah E Reisman; S B Jennifer Kan; Frances H Arnold
Journal:  ACS Catal       Date:  2020-06-04       Impact factor: 13.084

7.  A General Approach to Stereospecific Cross-Coupling Reactions of Nitrogen-Containing Stereocenters.

Authors:  Xinghua Ma; Haoran Zhao; Meruyert Binayeva; Glenn Ralph; Mohamed Diane; Shibin Zhao; Chao-Yuan Wang; Mark R Biscoe
Journal:  Chem       Date:  2020-03-02       Impact factor: 22.804

8.  Cobalt-Catalyzed Carbonylative Cross-Coupling of Alkyl Tosylates and Dienes: Stereospecific Synthesis of Dienones at Low Pressure.

Authors:  Brendon T Sargent; Erik J Alexanian
Journal:  J Am Chem Soc       Date:  2017-08-29       Impact factor: 15.419

9.  Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles.

Authors:  Zhaobin Wang; Shoshana Bachman; Alexander S Dudnik; Gregory C Fu
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-19       Impact factor: 15.336

10.  A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters.

Authors:  Jens Schmidt; Junwon Choi; Albert Tianxiang Liu; Martin Slusarczyk; Gregory C Fu
Journal:  Science       Date:  2016-12-08       Impact factor: 47.728
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