Literature DB >> 25413676

An efficient route to highly enantioenriched tetrahydroazulenes and β-tetralones by desymmetrization reactions of δ,δ-diaryldiazoaceto-acetates.

Yuxiao Liu1, Yongming Deng, Peter Y Zavalij, Renhua Liu, Michael P Doyle.   

Abstract

A highly stereoselective desymmetrization reaction of δ,δ-diaryl-α-diazo-β-ketoesters catalyzed by chiral dirhodium carboxylates forms aromatic cycloaddition products in up to 97% ee.

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Year:  2015        PMID： 25413676     DOI： 10.1039/c4cc08255a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Hg(OTf)2 Catalyzed Intramolecular 1,4-Addition of Donor-Acceptor Cyclopropenes to Arenes.

Authors:  Yongming Deng; Changcheng Jing; Peter Y Zavalij; Michael P Doyle
Journal:  Org Lett       Date:  2015-08-21       Impact factor: 6.005

2.  Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds.

Authors:  Yongming Deng; Lynée A Massey; Yeray A Rodriguez Núñez; Hadi Arman; Michael P Doyle
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-24       Impact factor: 15.336

Review 3.  Cycloaddition reactions of enoldiazo compounds.

Authors:  Qing-Qing Cheng; Yongming Deng; Marianne Lankelma; Michael P Doyle
Journal:  Chem Soc Rev       Date:  2017-08-29       Impact factor: 54.564
  3 in total

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