Literature DB >> 25412982

Reactions of osmabenzene with silver/copper acetylides: from metallabenzene to benzene.

Feifei Han1, Jinhua Li, Hong Zhang, Tongdao Wang, Zhenyang Lin, Haiping Xia.   

Abstract

The transformations of metallabenzene to substituted benzenes have been achieved by reactions of osmabenzenes with silver/copper acetylides. In this investigation, novel tetraphenylphosphonium salts containing two phosphonium substituents on the same benzene ring are generated.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  benzene; heteroaromatics; metallabenzene; metallacycles; tetraphenylphosphonium salt

Year:  2014        PMID: 25412982     DOI: 10.1002/chem.201405220

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  2 in total

1.  Gas phase anion photoelectron spectroscopy and theoretical investigation of gold acetylide species.

Authors:  Peng Wang; Wenjing Zhang; Xi-Ling Xu; Jinyun Yuan; Hong-Guang Xu; Weijun Zheng
Journal:  J Chem Phys       Date:  2017-05-21       Impact factor: 3.488

2.  Occurrence of Double Bond in π-Aromatic Rings: An Easy Way to Design Doubly Aromatic Carbon-Metal Structures.

Authors:  Nikolay V Tkachenko; Alvaro Muñoz-Castro; Alexander I Boldyrev
Journal:  Molecules       Date:  2021-11-29       Impact factor: 4.411

  2 in total

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