| Literature DB >> 25407494 |
Benjamin A Glassy1, Brandi M Cossairt.
Abstract
The synthesis and characterization of crystalline colloidal zinc phosphide quantum dots with observable excitonic transitions ranging between 424-535 nm (2.3-2.9 eV) are reported. A ternary combination of ZnEt2, Zn(O2CR)2, and P(SiMe3)3, forms a pentanuclear zinc cluster on mixing followed by conversion to (Et2Zn)P(ZnO2CR)2(SiMe3) in a rate-determining step prior to quantum dot formation.Entities:
Year: 2015 PMID： 25407494 DOI： 10.1039/c4cc08068h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222