Literature DB >> 25406376

Noteworthy performance of La(1-x)Ca(x)MnO3 perovskites in generating H2 and CO by the thermochemical splitting of H2O and CO2.

Sunita Dey1, B S Naidu, A Govindaraj, C N R Rao.   

Abstract

Perovskite oxides of the composition La1-xCaxMnO3 (LCM) have been investigated for the thermochemical splitting of H2O and CO2 to produce H2 and CO, respectively. The study was carried out in comparison with La1-xSrxMnO3, CeO2 and other oxides. The LCM system exhibits superior characteristics in high-temperature evolution of oxygen, and in reducing CO2 to CO and H2O to H2. The best results were obtained with La0.5Ca0.5MnO3 whose performance is noteworthy compared to that of other oxides including ceria. The orthorhombic structure of LCM seems to be a crucial factor.

Entities:  

Year:  2015        PMID: 25406376     DOI: 10.1039/c4cp04578e

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  6 in total

1.  Solar thermochemical splitting of water to generate hydrogen.

Authors:  C N R Rao; Sunita Dey
Journal:  Proc Natl Acad Sci U S A       Date:  2017-05-18       Impact factor: 11.205

2.  Tunable thermodynamic activity of La x Sr1-x Mn y Al1-y O3-δ (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) perovskites for solar thermochemical fuel synthesis.

Authors:  M Ezbiri; M Takacs; D Theiler; R Michalsky; A Steinfeld
Journal:  J Mater Chem A Mater       Date:  2017-01-23

3.  Solar thermochemical CO2 splitting with doped perovskite LaCo0.7Zr0.3O3: thermodynamic performance and solar-to-fuel efficiency.

Authors:  Lei Wang; Tianzeng Ma; Shaomeng Dai; Ting Ren; Zheshao Chang; Mingkai Fu; Xin Li; Yong Li
Journal:  RSC Adv       Date:  2020-09-29       Impact factor: 4.036

4.  Thermochemical CO2 splitting performance of perovskite coated porous ceramics.

Authors:  Amir Masoud Parvanian; Hamidreza Salimijazi; Mehdi Shabaninejad; Ulrike Troitzsch; Peter Kreider; Wojciech Lipiński; Mohammad Saadatfar
Journal:  RSC Adv       Date:  2020-06-17       Impact factor: 3.361

5.  ZnO-ZnCr2O4 composite prepared by a glycine nitrate process method and applied for hydrogen production by steam reforming of methanol.

Authors:  Chung-Lun Yu; Subramanian Sakthinathan; Guan-Ting Lai; Chia-Cheng Lin; Te-Wei Chiu; Ming-Che Liu
Journal:  RSC Adv       Date:  2022-08-10       Impact factor: 4.036

6.  Design principles of perovskites for solar-driven thermochemical splitting of CO2.

Authors:  Miriam Ezbiri; Michael Takacs; Boris Stolz; Jeffrey Lungthok; Aldo Steinfeld; Ronald Michalsky
Journal:  J Mater Chem A Mater       Date:  2017-07-03
  6 in total

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