Literature DB >> 25405630

Mechanistic insight into size-dependent activity and durability in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane.

Wenyao Chen1, Jian Ji, Xiang Feng, Xuezhi Duan, Gang Qian, Ping Li, Xinggui Zhou, De Chen, Weikang Yuan.   

Abstract

We report a size-dependent activity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane. Kinetic study and model calculations revealed that Pt(111) facet is the dominating catalytically active surface. There is an optimized Pt particle size of ca. 1.8 nm. Meanwhile, the catalyst durability was found to be highly sensitive to the Pt particle size. The smaller Pt particles appear to have lower durability, which could be related to more significant adsorption of B-containing species on Pt surfaces as well as easier changes in Pt particle size and shape. The insights reported here may pave the way for the rational design of highly active and durable Pt catalysts for hydrogen generation.

Entities:  

Year:  2014        PMID： 25405630     DOI： 10.1021/ja509778y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

1.  A Tunable Multivariate Metal-Organic Framework as a Platform for Designing Photocatalysts.

Authors:  Yang Wang; Hao Lv; Erik Svensson Grape; Carlo Alberto Gaggioli; Akhil Tayal; Aditya Dharanipragada; Tom Willhammar; A Ken Inge; Xiaodong Zou; Ben Liu; Zhehao Huang
Journal:  J Am Chem Soc       Date:  2021-04-26       Impact factor: 15.419

2.  An efficient on-board metal-free nanocatalyst for controlled room temperature hydrogen production.

Authors:  Saswati Santra; Debanjan Das; Nirmalya Sankar Das; Karuna Kar Nanda
Journal:  Chem Sci       Date:  2017-01-30       Impact factor: 9.825

3.  Covalent triazine framework supported non-noble metal nanoparticles with superior activity for catalytic hydrolysis of ammonia borane: from mechanistic study to catalyst design.

Authors:  Zhao Li; Teng He; Lin Liu; Weidong Chen; Miao Zhang; Guotao Wu; Ping Chen
Journal:  Chem Sci       Date:  2016-08-30       Impact factor: 9.825

4.  Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles.

Authors:  Chunyang Dong; Cheng Lian; Songchang Hu; Zesheng Deng; Jianqiu Gong; Mingde Li; Honglai Liu; Mingyang Xing; Jinlong Zhang
Journal:  Nat Commun       Date:  2018-03-28       Impact factor: 14.919

5.  Influence of the Water/Titanium Alkoxide Ratio on the Morphology and Catalytic Activity of Titania-Nickel Composite Particles for the Hydrolysis of Ammonia Borane.

Authors:  Tetsuo Umegaki; Yoshifumi Yamamoto; Qiang Xu; Yoshiyuki Kojima
Journal:  ChemistryOpen       Date:  2018-08-15       Impact factor: 2.911

6.  Synergistic Pt-WO3 Dual Active Sites to Boost Hydrogen Production from Ammonia Borane.

Authors:  Wenyao Chen; Wenzhao Fu; Gang Qian; Bingsen Zhang; Xuezhi Duan; Xinggui Zhou
Journal:  iScience       Date:  2020-02-19

7.  Enhanced hydrogen generation by reverse spillover effects over bicomponent catalysts.

Authors:  Zhe Gao; Guofu Wang; Tingyu Lei; Zhengxing Lv; Mi Xiong; Liancheng Wang; Shuangfeng Xing; Jingyuan Ma; Zheng Jiang; Yong Qin
Journal:  Nat Commun       Date:  2022-01-10       Impact factor: 17.694

8.  Bottom-up precise synthesis of stable platinum dimers on graphene.

Authors:  Huan Yan; Yue Lin; Hong Wu; Wenhua Zhang; Zhihu Sun; Hao Cheng; Wei Liu; Chunlei Wang; Junjie Li; Xiaohui Huang; Tao Yao; Jinlong Yang; Shiqiang Wei; Junling Lu
Journal:  Nat Commun       Date:  2017-10-20       Impact factor: 14.919

9.  Ni0.5Cu0.5Co2O4 Nanocomposites, Morphology, Controlled Synthesis, and Catalytic Performance in the Hydrolysis of Ammonia Borane for Hydrogen Production.

Authors:  Yufa Feng; Jin Zhang; Huilong Ye; Liling Li; Huize Wang; Xian Li; Xibin Zhang; Hao Li
Journal:  Nanomaterials (Basel)       Date:  2019-09-18       Impact factor: 5.076

10.  Gold catalysts containing interstitial carbon atoms boost hydrogenation activity.

Authors:  Yafei Sun; Yueqiang Cao; Lili Wang; Xiaotong Mu; Qingfei Zhao; Rui Si; Xiaojuan Zhu; Shangjun Chen; Bingsen Zhang; Ying Wan
Journal:  Nat Commun       Date:  2020-09-14       Impact factor: 14.919
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