Literature DB >> 25399924

Metallofullerenes encaging mixed-metal clusters: synthesis and structural studies of Gdx Ho3-x N@C80 and Gdx Lu3-x N@C80.

Zhuxia Zhang1, Yang Liu, Peide Han, Shengyi Zhuang, Taishan Wang, Shuchang Luo, Bingshe Xu.   

Abstract

Metallofullerenes of Gdx Ho3-x N@C80 and Gdx Lu3-x N@C80 encapsulating mixed-metal nitride clusters were synthesized. Spectroscopic characterization of Gdx Ho3-x N@C80 and Gdx Lu3-x N@C80 was employed to reveal their structural and vibrational properties. The structural properties of these species were analyzed by using theoretical calculations. The studies of Gdx Ho3-x N@C80 and Gdx Lu3-x N@C80 laid the foundations for these species to be used as multifunctional molecules.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  absorption; cage compounds; endofullerenes; theoretical calculations; vibrational properties

Year:  2014        PMID： 25399924     DOI： 10.1002/cphc.201402679

Source DB:  PubMed          Journal:  Chemphyschem        ISSN： 1439-4235            Impact factor:   3.102


  2 in total

1.  Single-Molecule Magnets DyM2 N@C80 and Dy2 MN@C80 (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy3+ Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling, and Mixing of Molecular and Lattice Vibrations.

Authors:  Lukas Spree; Christin Schlesier; Aram Kostanyan; Rasmus Westerström; Thomas Greber; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov
Journal:  Chemistry       Date:  2020-02-06       Impact factor: 5.236

2.  Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism.

Authors:  Ariane Brandenburg; Denis S Krylov; Alexander Beger; Anja U B Wolter; Bernd Büchner; Alexey A Popov
Journal:  Chem Commun (Camb)       Date:  2018-09-20       Impact factor: 6.222
  2 in total

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