Literature DB >> 25386787

Synthesis of gem-difluorinated nitroso compounds.

Vladimir O Smirnov1, Marina I Struchkova, Dmitry E Arkhipov, Alexander A Korlyukov, Alexander D Dilman.   

Abstract

A method for the synthesis of gem-difluorinated nitroso compounds is described. The reaction involves interaction of organozinc reagents with (bromodifluoromethyl)trimethylsilane followed by nitrosation of difluorinated organozinc species with an n-butyl nitrite/chlorotrimethylsilane system.

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Year:  2014        PMID: 25386787     DOI: 10.1021/jo5023537

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

Review 1.  Recent advances in the synthesis of fluorinated hydrazones.

Authors:  Rui Guo; Junting Chen
Journal:  RSC Adv       Date:  2018-05-10       Impact factor: 3.361

2.  Coupling of α,α-difluoro-substituted organozinc reagents with 1-bromoalkynes.

Authors:  Artem A Zemtsov; Alexander D Volodin; Vitalij V Levin; Marina I Struchkova; Alexander D Dilman
Journal:  Beilstein J Org Chem       Date:  2015-11-10       Impact factor: 2.883

  2 in total

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