| Literature DB >> 25385329 |
Dawei Feng1, Kecheng Wang, Jie Su, Tian-Fu Liu, Jihye Park, Zhangwen Wei, Mathieu Bosch, Andrey Yakovenko, Xiaodong Zou, Hong-Cai Zhou.
Abstract
Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm(3) g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.Entities:
Keywords: carboxylate ligands; host-guest systems; mesoporous materials; metal-organic frameworks; zirconium
Year: 2014 PMID: 25385329 DOI: 10.1002/anie.201409334
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336