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Literature DB >> 25384179

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet.

Nicholas F Chilton¹, Conrad A P Goodwin, David P Mills, Richard E P Winpenny.

Abstract

We report the first near-linear bis(amide) 4f-block compound and show that this novel structure, if implemented with dysprosium(III), would have unprecedented single molecule magnet (SMM) properties with an energy barrier, Ueff, for reorientation of magnetization of 1800 cm(-1).

Entities: Chemical

Year: 2015 PMID： 25384179 DOI： 10.1039/c4cc08312a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

13 in total

Review 1. Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.

Authors: Fabrizio Ortu
Journal: Chem Rev Date: 2022-01-31 Impact factor: 60.622

2. The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

Authors: Jamie M Frost; Katie L M Harriman; Muralee Murugesu
Journal: Chem Sci Date: 2015-12-23 Impact factor: 9.825

3. Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets.

Authors: Katie L M Harriman; Jennifer J Le Roy; Liviu Ungur; Rebecca J Holmberg; Ilia Korobkov; Muralee Murugesu
Journal: Chem Sci Date: 2016-08-08 Impact factor: 9.825

4. Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides.

Authors: Conrad A P Goodwin; Benjamin L L Réant; Gianni F Vettese; Jon G C Kragskow; Marcus J Giansiracusa; Ida M DiMucci; Kyle M Lancaster; David P Mills; Stephen Sproules
Journal: Inorg Chem Date: 2020-05-18 Impact factor: 5.165

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet.

Review 1. Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.

2. The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

3. Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets.

4. Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides.

5. Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands.

6. An air-stable Dy(iii) single-ion magnet with high anisotropy barrier and blocking temperature.

7. Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L₃-edge X-ray absorption spectroscopy.

8. Quantum tunnelling of the magnetisation in single-molecule magnet isotopologue dimers.

9. Cis-trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets.

10. Structural Characterization of Lithium and Sodium Bulky Bis(silyl)amide Complexes.