| Literature DB >> 25384160 |
Yu Tang1, Ji-tian Liu, Ping Chen, Ming-can Lv, Zhen-zhen Wang, Yi-kun Huang.
Abstract
A concise, stereoselective, and protecting-group-free total synthesis of aplykurodinone-1 from Hajos-Parrish ketone was described. The synthetic approach features a sequence of aerobic allylic oxidation and elimination of alcohol 9. The key intermediate for this synthesis was formed by a stereoselective intramolecular radical cyclization.Entities:
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Year: 2014 PMID： 25384160 DOI： 10.1021/jo501684k
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354