Literature DB >> 25383743

Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide.

Matthew D Jones1, Stuart L Hancock, Paul McKeown, Pascal M Schäfer, Antoine Buchard, Lynne H Thomas, Mary F Mahon, John P Lowe.   

Abstract

Herein we report the synthesis and characterisation of a series of Zr(IV) 2,2'-bipyrrolidine-salan derived complexes and their exploitation for the ring opening polymerisation of rac-lactide to afford highly isotactically enriched polymers.

Entities:  

Year:  2014        PMID： 25383743     DOI： 10.1039/c4cc07871c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Phosphasalen Indium Complexes Showing High Rates and Isoselectivities in rac-Lactide Polymerizations.

Authors:  Dominic Myers; Andrew J P White; Craig M Forsyth; Mark Bown; Charlotte K Williams
Journal:  Angew Chem Int Ed Engl       Date:  2017-04-05       Impact factor: 15.336

2.  Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide.

Authors:  Matthew D Jones; Lauren Brady; Paul McKeown; Antoine Buchard; Pascal M Schäfer; Lynne H Thomas; Mary F Mahon; Timothy J Woodman; John P Lowe
Journal:  Chem Sci       Date:  2015-06-17       Impact factor: 9.825
  2 in total

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