Literature DB >> 25380031

Rim-functionalized cryptophane-111 derivatives via heterocapping, and their xenon complexes.

Akil I Joseph1, Gracia El-Ayle, Céline Boutin, Estelle Léonce, Patrick Berthault, K Travis Holman.   

Abstract

Capping of cyclotriphenolene (3a) by the more available cyclotriguaiacylene (3c) or trisbromocyclotriphenolene (3b) gives the first rim-functionalized cryptophane-111 derivatives. Crystal structures of the xenon complexes reveal high cavity packing coefficients and unprecedentedly short Xe···C contacts.

Entities:  

Year:  2014        PMID: 25380031     DOI: 10.1039/c4cc08001g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Limitations and extensions of the lock-and-key principle: differences between gas state, solution and solid state structures.

Authors:  Hans-Jörg Schneider
Journal:  Int J Mol Sci       Date:  2015-03-25       Impact factor: 5.923

  1 in total

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