Literature DB >> 25377546

Platinum(II) olefin hydroarylation catalysts: tuning selectivity for the anti-Markovnikov product.

Marie L Clement1, Kyle A Grice, Avery T Luedtke, Werner Kaminsky, Karen I Goldberg.   

Abstract

Pt(II) complexes containing unsymmetrical (pyridyl)pyrrolide ligands are shown to catalyze the hydroarylation of unactivated alkenes with selectivity for the anti-Markovnikov product. Substitution on the pyrrolide portion of the ligand allows effective tuning of the selectivity to anti-Markovnikov alkylarene products, whereas substitution on the pyridyl portion can promote competitive alkenylarene production.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  (pyridyl)pyrrolide; CH activation; hydroarylation; olefins; platinum

Year:  2014        PMID： 25377546     DOI： 10.1002/chem.201405174

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  2 in total

1.  Direct C(sp2)-H alkylation of unactivated arenes enabled by photoinduced Pd catalysis.

Authors:  Daeun Kim; Geun Seok Lee; Dongwook Kim; Soon Hyeok Hong
Journal:  Nat Commun       Date:  2020-10-19       Impact factor: 14.919

2.  Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions.

Authors:  Noam I Saper; Akito Ohgi; David W Small; Kazuhiko Semba; Yoshiaki Nakao; John F Hartwig
Journal:  Nat Chem       Date:  2020-02-10       Impact factor: 24.427
  2 in total

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