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Literature DB >> 25376102

Frustrated Lewis pair activation of an N-sulfinylamine: a source of sulfur monoxide.

Lauren E Longobardi¹, Vanessa Wolter, Douglas W Stephan.

Abstract

Inter- and intramolecular P/B frustrated Lewis pairs are shown to react with an N-sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine-borane-stabilized sulfur monoxide complexes, and indeed these species act as sources of SO, effecting the oxidation of PPh3 and delivering SO to [RhCl(PPh3)3] and an N-heterocyclic carbene.

Entities: Chemical Disease Gene

Keywords: carbenes; frustrated Lewis pairs; phosphinimine-boranes; rhodium; sulfur monoxide

Year: 2014 PMID： 25376102 DOI： 10.1002/anie.201409969

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

5 in total

1. Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity.

Authors: Maximilian Joost; Matthew Nava; Wesley J Transue; Marie-Aline Martin-Drumel; Michael C McCarthy; David Patterson; Christopher C Cummins
Journal: Proc Natl Acad Sci U S A Date: 2018-05-17 Impact factor: 11.205

Review 2. Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties.

Authors: Jennifer Yuan; Zhen Xu; Michael O Wolf
Journal: Chem Sci Date: 2022-04-28 Impact factor: 9.969

Frustrated Lewis pair activation of an N-sulfinylamine: a source of sulfur monoxide.

1. Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity.

Review 2. Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties.

3. Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N₂O reduction.

4. Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations.

5. An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair.

Frustrated Lewis pair activation of an N-sulfinylamine: a source of sulfur monoxide.

1. Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity.

Review 2. Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties.

3. Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction.

4. Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations.

5. An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair.

3. Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N₂O reduction.