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Literature DB >> 25367639

Quinone diazides for olefin functionalization.

Abstract

The utility of quinone diazides in materials science is vast and well-documented, yet this potentially useful motif has languished in the annals of organic synthesis. Herein we show that modern tools of catalysis can be employed with free or suitably masked quinone diazides to unleash the power of these classic diazo compounds in the context of both inter- and intramolecular olefin cyclopropanation.

Entities: Chemical

Keywords: olefin functionalization; quinone diazide; steroids; triazenes

Mesh：

Substances：

Year: 2014 PMID： 25367639 DOI： 10.1002/anie.201408022

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

4 in total

1. Modular Total Synthesis and Cell-Based Anticancer Activity Evaluation of Ouabagenin and Other Cardiotonic Steroids with Varying Degrees of Oxygenation.

Authors: Hem Raj Khatri; Bijay Bhattarai; Will Kaplan; Zhongzheng Li; Marcus John Curtis Long; Yimon Aye; Pavel Nagorny
Journal: J Am Chem Soc Date: 2019-03-14 Impact factor: 15.419

Quinone diazides for olefin functionalization.

1. Modular Total Synthesis and Cell-Based Anticancer Activity Evaluation of Ouabagenin and Other Cardiotonic Steroids with Varying Degrees of Oxygenation.

2. Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods.

3. Enantioselective Spirocyclopropanation of para-Quinone Methides Using Ammonium Ylides.

4. Unravelling Photochemical Relationships Among Natural Products from Aplysia dactylomela.