Literature DB >> 25366300

Reversible capping/uncapping of phosphorous-centered Keggin-type polyoxoniobate clusters.

Jung-Ho Son1, William H Casey.   

Abstract

Caps in α-Keggin-type polyoxometalates [PM2Nb12O40](9-) (M: Nb[double bond, length as m-dash]O or V[double bond, length as m-dash]O) can be removed in basic condition to produce uncapped [PNb12O40](15-). Transmetalation or capping occurs from the reaction of [PNb14O42](9-) or [PNb12O40](15-) with either Sb2O3 or V2O5 to form [PSb2Nb12O40](9-) or [PV2Nb12O42](9-), respectively.

Entities:  

Year:  2015        PMID： 25366300     DOI： 10.1039/c4cc05689b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Controllable Assembly of Vanadium-Containing Polyoxoniobate-Based Materials and Their Electrocatalytic Activity for Selective Benzyl Alcohol Oxidation.

Authors:  Xiaoxia Li; Ni Zhen; Chengpeng Liu; Di Zhang; Jing Dong; Yingnan Chi; Changwen Hu
Journal:  Molecules       Date:  2022-04-30       Impact factor: 4.927

2.  Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids.

Authors:  Dorothea Voß; Sebastian Ponce; Stefanie Wesinger; Bastian J M Etzold; Jakob Albert
Journal:  RSC Adv       Date:  2019-09-17       Impact factor: 3.361

3.  Synthesis, structure, and luminescent properties of a family of lanthanide-functionalized peroxoniobiophosphates.

Authors:  Haiying Wang; Jing Li; Junjun Sun; Yaya Wang; Zhijie Liang; Pengtao Ma; Dongdi Zhang; Jingping Wang; Jingyang Niu
Journal:  Sci Rep       Date:  2017-09-06       Impact factor: 4.379
  3 in total

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