Literature DB >> 25347688

Exploitation of the majority rules effect for the accurate measurement of high enantiomeric excess values using CD spectroscopy.

Helen M Seifert1, Yun-Bao Jiang, Eric V Anslyn.   

Abstract

A new method for lowering the error of CD based methods for measuring high enantiomeric excess values is described, which exploits the majority rules effect exhibited by certain helical polymers. A proof of principle experiment was conducted.

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Year:  2014        PMID： 25347688     DOI： 10.1039/c4cc07927b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  A racemate-rules effect supramolecular polymer for ee determination of malic acid in the high ee region.

Authors:  Xuan-Xuan Chen; Yun-Bao Jiang; Eric V Anslyn
Journal:  Chem Commun (Camb)       Date:  2016-10-18       Impact factor: 6.222

Review 2.  Helical Polyacetylenes Induced via Noncovalent Chiral Interactions and Their Applications as Chiral Materials.

Authors:  Katsuhiro Maeda; Eiji Yashima
Journal:  Top Curr Chem (Cham)       Date:  2017-07-20

Review 3.  Chiral assembly of organic luminogens with aggregation-induced emission.

Authors:  Chenchen Liu; Jun-Cheng Yang; Jacky W Y Lam; Hai-Tao Feng; Ben Zhong Tang
Journal:  Chem Sci       Date:  2021-06-10       Impact factor: 9.825

4.  A rapid and sensitive method for chiroptical sensing of α-amino acids via click-like labeling with o-phthalaldehyde and p-toluenethiol.

Authors:  Bo Li; Jie Zhang; Li Li; Gong Chen
Journal:  Chem Sci       Date:  2020-12-22       Impact factor: 9.825

5.  Helical springs as a color indicator for determining chirality and enantiomeric excess.

Authors:  Katsuhiro Maeda; Daisuke Hirose; Mai Nozaki; Yoichi Shimizu; Taro Mori; Kentaro Yamanaka; Koji Ogino; Tatsuya Nishimura; Tsuyoshi Taniguchi; Munetsugu Moro; Eiji Yashima
Journal:  Sci Adv       Date:  2021-06-30       Impact factor: 14.136
  5 in total

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